Propoxylated Polyol for Low-Temperature Detergent Cleaning

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Solution Overview

Problem

Current detergent formulations face challenges in removing oily/fatty and clay soils at low temperatures, with reduced surfactant levels and the need for biodegradable polymers that provide both primary and secondary cleaning benefits, while also ensuring environmental sustainability and reduced CO2 emissions.

Innovation Solution

Development of propoxylated polyols with a polyol core consisting of four to five hydroxyl groups, modified with polypropylene oxide branches, which demonstrate excellent wash performance and significant biodegradability, allowing for effective soil removal and whiteness maintenance in laundry detergents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-generated harmful factors

If surfactant levels are reduced in cleaning detergents, then environmental sustainability and cost are improved, but oily/fatty stain removal capability deteriorates

Engineering Contradiction:
Improveenvironmental impactVSAvoidoily/fatty stain removal
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The invention uses a composite cleaning system combining propoxylated polyol (a biodegradable polymer) with reduced levels of traditional surfactants. The polyol component provides grease cleaning capabilities through its amphiphilic structure, while the reduced surfactant formulation decreases environmental harm. This composite approach allows the detergent to maintain effective oily stain removal while achieving lower anionic surfactant content for improved sustainability.

Inventive Principle:
Principle #40Composite materials

2Use of energy by stationary object

If washing temperature is decreased, then energy consumption and environmental sustainability are improved, but grease cleaning capability deteriorates

Engineering Contradiction:
Improveenergy consumptionVSAvoidgrease cleaning capability
Core Design Contradiction:
Use of energy by stationary objectVSReliability

Solution Approach 1:

The invention changes the chemical parameters of the cleaning system by introducing propoxylated polyol with specific molecular weight and hydroxyl group content. This polymer provides cold water solubility and effective grease cleaning at low temperatures through its unique structure, enabling the detergent to maintain grease removal performance without requiring high washing temperatures, thus reducing energy consumption.

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If biodegradable polymers are used, then environmental sustainability is improved, but cleaning performance may deteriorate

Engineering Contradiction:
Improveenvironmental persistenceVSAvoidcleaning performance
Core Design Contradiction:
Object-generated harmful factorsVSReliability

Solution Approach 1:

The invention optimizes specific parameters of the biodegradable polymer including molecular weight (700-10,000 g/mol), hydroxyl group content (4-5 groups), and propylene oxide unit count (16-30 units). These parameter optimizations ensure the polymer achieves adequate biodegradability while maintaining effective cleaning performance for both oily/fatty and particulate soils, resolving the trade-off between environmental sustainability and cleaning efficacy.

Inventive Principle:
Principle #35Parameter changes

4Loss of substance

If detergent formulations are compacted, then water usage and transportation costs are reduced, but weight-efficiency requirements increase

Engineering Contradiction:
Improvewater usageVSAvoidweight-efficiency
Core Design Contradiction:
Loss of substanceVSProductivity

Solution Approach 1:

The propoxylated polyol provides high weight-efficiency cleaning performance, allowing reduced detergent dosing in compacted formulations. The polymer's multi-functionality (grease cleaning, particulate soil removal, whiteness maintenance) means smaller amounts are needed to achieve effective cleaning, enabling detergent compaction while maintaining or improving weight-efficiency.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS20240400943A1Fabric and home care composition comprising a propoxylated polyol
Publication Date: 2024.12.05 PROCTER & GAMBLE CO
  • US20240400943A1 patent drawing
  • US20240400943A1 patent drawing
  • US20240400943A1 patent drawing

AI summary

Biodegradable polyol propoxylates, their preparation, uses, and compositions including them.This invention deals with biodegradable polyol propoxylates based on polyols possessing four to five —OH groups, their manufacture and uses, for example in laundry or dishwashing.