Protease Clearcoat for Enzymatic Insect Stain Removal

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Solution Overview

Problem

Existing self-cleaning coatings are ineffective in removing biological stains, particularly from insect sources, due to their reliance on passive hydrophobic and oleophobic properties, which fail on high-gloss surfaces, and photocatalytic coatings are limited by oxidative degradation of polymer resins.

Innovation Solution

Incorporating a protease, such as thermolysin-like proteases from Bacillus stearothermophilus, into or onto polymer composite materials to enzymatically degrade biological stain components, facilitating active removal through gentle rinsing.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional self-cleaning coatings based on water rolling or sheeting are used, then inorganic dirt removal is improved, but biological stain removal is worsened

Engineering Contradiction:
Improveinorganic dirt removal efficiencyVSAvoidbiological stain removal effectiveness
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The invention changes the cleaning mechanism from passive physical removal (water rolling) to active enzymatic degradation. By incorporating protease enzymes into the coating formulation, the system transforms how biological stains are removed - through biochemical breakdown of protein-based components rather than relying on water sheeting alone. This parameter change enables effective removal of both inorganic and biological stains.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention creates a composite coating material that combines traditional self-cleaning coating components with protease enzymes. This composite structure integrates the hydrophobic/oleophobic properties of conventional coatings with the biological degradation capability of enzymes, achieving dual functionality for removing both inorganic and organic stains including insect bodies, bird droppings, and other biological contaminants.

Inventive Principle:
Principle #40Composite materials

2Productivity

If photocatalytic coatings with TiO2 are used, then organic stain decomposition is improved, but polymer coating degradation is worsened

Engineering Contradiction:
Improveorganic stain decomposition rateVSAvoidpolymer coating integrity
Core Design Contradiction:
ProductivityVSStability of the object's composition

Solution Approach 1:

The invention introduces protease enzymes as intermediary agents that selectively target and degrade biological stains without affecting the polymer coating matrix. Unlike TiO2 photocatalysis which generates non-selective oxidative radicals that attack both stains and coating polymers, proteases act as specific biological catalysts that recognize and break down protein-based stain components while leaving the synthetic polymer coating intact. This intermediary approach enables stain removal while preserving coating stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The enzymatic cleaning mechanism provides local quality by targeting specific biological stain components (proteins, peptides) rather than acting on all organic materials indiscriminately. The protease enzymes are embedded within the coating matrix and activate only when biological stains are present, providing localized degradation action at the stain-coating interface without generating widespread oxidative damage to the polymer structure.

Inventive Principle:
Principle #3Local quality

3Ease of operation

If passive hydrophobic and oleophobic coatings are used, then water and oil repellency is improved, but insect stain removal on high-gloss surfaces is worsened

Engineering Contradiction:
Improvewater and oil repellencyVSAvoidinsect stain removal efficiency
Core Design Contradiction:
Ease of operationVSProductivity

Solution Approach 1:

The coating incorporates protease enzymes that provide self-service cleaning capability by automatically degrading insect stains upon contact. The enzymes remain dormant within the coating matrix and become activated when biological stains are present, enabling the coating to self-clean without requiring external intervention such as washing or mechanical scrubbing. This self-service mechanism works effectively on high-gloss surfaces where passive hydrophobic coatings fail.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The protease enzymes are pre-incorporated into the coating formulation during manufacturing, preparing the coating with built-in biological cleaning capability before application. This preliminary action ensures that the coating is pre-equipped with enzymatic activity that can immediately begin degrading insect stains upon contact, rather than requiring subsequent treatment or activation steps.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The protease-based coatings effectively break down and remove biological stains, including insect stains, with improved performance compared to enzyme-free controls and other protease types, demonstrating enhanced self-cleaning functionality without degrading the coating materials.

Implementation Method 1

protease...capable of enzymatically degrading a component of a biological stain

Methodology Applied
Scientific EffectEnzymatic degradation: Enzyme

Implementation Method 2

protease...enzymatically degrading...biological stain components

Methodology Applied
Scientific EffectHydrolysis: Hydrolysis

Data Source

PatentUS8796009B2Clearcoat containing thermolysin-like protease from <i>Bacillus stearothermophilus </i>for cleaning of insect body stains
Publication Date: 2014.08.05 TOYOTA MOTOR CO LTD
  • US8796009B2 patent drawing
  • US8796009B2 patent drawing
  • US8796009B2 patent drawing

AI summary

A substrate or coating is provided that includes a protease with enzymatic activity toward a component of a biological stain. Also provided is a process for facilitating the removal of a biological stain is provided wherein an inventive substrate or coating including a protease is capable of enzymatically degrading of one or more components of the biological stain to facilitate biological stain removal from the substrate or said coating.