Protective Coating for Polymeric Seals in Fluorinated Insulation

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Solution Overview

Problem

The use of organofluorine compounds in dielectric insulation gases can lead to a reduction in insulation and arc extinction performance over prolonged operation times, potentially requiring premature maintenance and replacement of components, especially those made of polymeric materials which are sensitive to exposure.

Innovation Solution

Applying a protective layer of a second material with a thickness of at least 50 μm on solid components exposed to the insulation fluid, which prevents direct contact and reaction with the organofluorine compound, maintaining the integrity of both the insulation fluid and components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If polymeric sealing components are used in apparatus with organofluorine compound insulation gas, then the apparatus can be manufactured with standard materials and lower cost, but the sealing components become sensitive to organofluorine compound exposure and degrade over time

Engineering Contradiction:
ImprovemanufacturabilityVSAvoidcomponent stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

A protective coating layer is applied to the sealing components, acting as an intermediary barrier between the polymeric material and the organofluorine compound insulation gas. This coating prevents direct contact and chemical reaction, allowing the use of standard polymeric sealing materials without degradation from exposure to the insulation gas.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The surface properties of the sealing components are modified by applying a protective coating that changes the chemical interaction parameters between the component material and the insulation gas. This coating alters the surface chemistry to be incompatible with organofluorine compounds, preventing degradation while maintaining the bulk material properties.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If standard polymeric sealing materials are exposed to organofluorine compound insulation gas over prolonged periods, then the apparatus can operate continuously, but the insulation gas composition changes due to decomposition reactions

Engineering Contradiction:
Improveoperational lifetimeVSAvoidinsulation gas composition
Core Design Contradiction:
Duration of action of stationary objectVSStability of the object's composition

Solution Approach 1:

The protective coating on sealing components serves as a barrier that prevents organofluorine compounds from reacting with the polymeric material, thereby preventing the release of decomposition products into the insulation gas and maintaining gas composition stability during prolonged operation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The reactive functional groups that would otherwise participate in decomposition reactions are effectively 'taken out' from the sealing component surface by the protective coating, eliminating the source of contamination that would alter insulation gas composition over time.

Inventive Principle:
Principle #2Taking out (Extraction)

3Ease of manufacture

If sealing components made of polymeric materials are used in the apparatus, then the apparatus can be manufactured with readily available materials, but the components require premature replacement due to sensitivity to organofluorine compound exposure

Engineering Contradiction:
Improvematerial availabilityVSAvoidmaintenance interval
Core Design Contradiction:
Ease of manufactureVSEase of repair

Solution Approach 1:

By applying a protective coating to sealing components, standard polymeric materials can be used without the degradation issues that would otherwise require premature replacement. This maintains material availability and ease of manufacture while extending maintenance intervals.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Reliability

If a protective coating is applied to sealing components to prevent reaction with organofluorine compounds, then component stability is improved, but device complexity increases due to additional manufacturing steps

Engineering Contradiction:
Improvecomponent stabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The protective coating modifies the surface parameters of sealing components to achieve chemical compatibility with organofluorine compounds. This relatively simple surface treatment approach improves component stability without requiring fundamental changes to the overall device architecture or complex multi-layer systems.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution extends the service lifetime of the apparatus by preventing decomposition reactions and maintaining mechanical and electrical properties, reducing maintenance needs and safety risks associated with decomposition products like hydrogen fluoride.

Implementation Method 1

the at least one solid component contains a basic body made of a first material and a protective layer made of a second material different from the first material, said protective layer being directly or indirectly applied on the basic body

Methodology Applied
Scientific EffectPhysical barrier (protective layer): Physical Containment

Data Source

PatentUS10818407B2Apparatus for the generation, distribution and/or usage of electrical energy and component for such an apparatus
Publication Date: 2020.10.27 HITACHI ENERGY LTD
  • US10818407B2 patent drawing
  • US10818407B2 patent drawing
  • US10818407B2 patent drawing

AI summary

The present invention relates to an electrical apparatus having an insulating space which contains a dielectric insulation fluid comprising an organofluorine compound. At least one solid component of the apparatus that is directly exposed to the insulation fluid contains a basic body made of a first material and a protective layer made of a second material different from the first material, the protective layer being directly or indirectly applied on the basic body and having a thickness of at least 50 μm. The organofluorine compound is selected from the group consisting of: fluoroethers, fluoroketones, fluoroolefins, fluoronitriles, and mixtures thereof, and the first material comprises or consists of a material selected from the group consisting of: a polymeric material, a ceramic, a composite material, and mixtures or combinations thereof.