Protein-Polyuronide Conjugates for pH-Stable Emulsions

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Solution Overview

Problem

Existing emulsifiers like lecithins and mono- and diglycerides are criticized by consumers, and proteins as emulsifiers have stability issues at extreme pH and temperature conditions, limiting food processing and application.

Innovation Solution

A protein-polyuronide conjugate is formed through a covalent bond between a plant protein (potato or rapeseed) and a polyuronide, preferably pectin, using a Maillard reaction, with partial or full esterification of polyuronide carboxylic acid groups to enhance stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional emulsifiers (lecithins, mono- and diglycerides) are used, then emulsion stability is achieved, but consumer acceptance decreases due to criticism of additives

Engineering Contradiction:
Improveemulsion stabilityVSAvoidconsumer criticism of additives
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent replaces conventional emulsifiers with a naturally occurring alternative: a complex formed by mixing a protein-containing ingredient (such as milk protein) with a polysaccharide-containing ingredient (such as pectin or guar gum). This naturally-derived complex performs the emulsification function without requiring synthetic or processed emulsifiers, thereby maintaining emulsion stability while eliminating consumer concerns about additives.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

2Object-affected harmful factors

If proteins are used as emulsifiers, then consumer acceptance improves due to natural ingredients, but stability decreases at extreme pH and temperature conditions

Engineering Contradiction:
Improveconsumer acceptanceVSAvoidemulsion stability
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent combines two natural ingredients - a protein-containing ingredient and a polysaccharide-containing ingredient - to form a complex that leverages the complementary strengths of both components. The protein provides natural emulsification properties acceptable to consumers, while the polysaccharide component enhances stability across a broader range of pH and temperature conditions. This synergistic combination resolves the contradiction between naturalness and stability.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention creates a composite emulsifying system by forming a complex between protein and polysaccharide molecules. This composite structure combines the amphiphilic properties of proteins with the gel-forming and stabilizing characteristics of polysaccharides, resulting in an emulsifier that maintains both consumer appeal (natural ingredients) and robust stability under varying processing and storage conditions.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The conjugate provides increased stability against pH and temperature variations, forming stable emulsions with small oil droplets, suitable for food and cosmetic products.

Implementation Method 1

A protein-polyuronide conjugate is formed through a covalent bond between a plant protein (potato or rapeseed) and a polyuronide, preferably pectin, using a Maillard reaction

Methodology Applied
Scientific EffectMaillard reaction: Chemical Bonding

Data Source

PatentEP3723499B1Protein-polyuronide conjugates and use thereof as emulsifiers
Publication Date: 2025.10.01 SYMRISE GMBH & CO KG
  • EP3723499B1 patent drawingFigure 1~2
  • EP3723499B1 patent drawingFigure 3~4
  • EP3723499B1 patent drawing

AI summary

The invention relates to protein-polyuronide conjugates, wherein at least one polyuronide is bonded to a protein by means of a covalent bond and the protein is of plant origin. The invention further relates to creaming-stable edible emulsions, beverage syrups, and ready-to-drink beverages, to the use of protein-polyuronide conjugates to produce foods and cosmetic or medical products, to the use of protein-polyuronide conjugates as emulsifiers, to a method for producing protein-polyuronide conjugates, and to the protein-polyuronide conjugates produced by means of the method.