PSA Tail Gas Molecular Weight Stabilization

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Solution Overview

Problem

Centrifugal gas compressors used in pressure swing adsorption (PSA) processes are sensitive to dynamic fluctuations in gas density, leading to inefficiencies and instability in compressing tail gas streams with varying molecular weights.

Innovation Solution

Synchronizing the cycling steps of multiple PSA units to ensure that one unit produces a high molecular weight tail gas while another produces a low molecular weight tail gas, and then combining these streams to reduce overall molecular weight fluctuation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single PSA unit is used to produce tail gas, then the process is simple, but the molecular weight fluctuates significantly during cycling

Engineering Contradiction:
Improvenumber of PSA unitsVSAvoidmolecular weight stability
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The patent combines multiple PSA units (specifically two or more) to operate in parallel, where their tail gas streams are merged together. This merging allows the compositional fluctuations of individual units to average out, stabilizing the overall molecular weight of the combined tail gas stream while maintaining the simplicity of using standard PSA technology.

Inventive Principle:
Principle #5Merging (Combining)

2Stability of the object's composition

If multiple PSA units are used to reduce molecular weight fluctuation, then composition stability improves, but system complexity increases

Engineering Contradiction:
Improvemolecular weight stabilityVSAvoidnumber of PSA units
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent employs periodic cycling of multiple PSA units with coordinated timing. Each unit operates through periodic cycles of adsorption, desorption, and regeneration phases. By synchronizing these periodic actions across multiple units, the system achieves stable average composition at the outlet while the individual units undergo their necessary cyclic operations.

Inventive Principle:
Principle #19Periodic action

3Productivity

If centrifugal compressor is used for large gas flow rates, then compression efficiency is high, but the compressor is sensitive to dynamic fluctuations in gas density

Engineering Contradiction:
Improvegas flow rate capacityVSAvoidcompression stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent implements preliminary stabilization of the tail gas composition before it enters the centrifugal compressor. By using multiple PSA units with coordinated cycling, the molecular weight fluctuation is reduced in advance, ensuring that the gas fed to the compressor has more stable density characteristics. This preliminary action protects the centrifugal compressor from harmful density fluctuations while maintaining its high productivity.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces molecular weight fluctuations in the combined tail gas stream, leading to more efficient and stable compression, lower power consumption, and improved stability for downstream processes.

Implementation Method 1

a first PSA separation zone comprising a plurality of vessels each containing an adsorbent configured to adsorb a species from a multi-component feed

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS20250196053A1Processes and apparatuses for reducing molecular weight fluctuation in a tail gas stream from a pressure swing adsorption process
Publication Date: 2025.06.19 UOP LLC
  • US20250196053A1 patent drawing
  • US20250196053A1 patent drawing

AI summary

Processes and apparatuses for reducing molecular weight fluctuation in a tail gas stream from a pressure swing adsorption process. Multiple PSA separation zone are synchronized such that when one of the PSA units is generating a low molecular weight tail gas, there is another PSA unit generating a high molecular weight tail gas.