Pseudo-Graphite Electrode for Chlorine Detection

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing electrodes for detecting chlorine species are costly and have low performance, with their effectiveness reduced by fouling and environmental interferences.

Innovation Solution

A pseudo-graphite electrode is coated onto a substrate and modified with amine groups or gold nanoparticles to enhance chlorine species detection, utilizing electrochemical methods for improved sensitivity and corrosion resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional electrodes are used for chlorine species detection, then detection capability is achieved, but cost is high and performance is low

Engineering Contradiction:
Improvedetection performanceVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the material parameters of the electrode by coating pseudo-graphite onto the electrode substrate surface. This material parameter change transforms the electrode from conventional materials to pseudo-graphite, achieving high performance detection with lower cost compared to traditional expensive electrodes

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by coating pseudo-graphite layer onto an electrode substrate. This composite material approach combines the advantages of the substrate with the superior electrochemical properties of pseudo-graphite, achieving both cost-effectiveness and high detection performance

Inventive Principle:
Principle #40Composite materials

2Reliability

If conventional electrodes are used for chlorine species detection, then detection function is provided, but electrode fouling occurs and performance is reduced

Engineering Contradiction:
Improvedetection stabilityVSAvoidelectrode fouling
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The patent changes the surface properties of the electrode by using pseudo-graphite coating, which has inherent anti-fouling characteristics. This parameter change in material composition prevents fouling accumulation and maintains stable detection performance over time

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a disposable pseudo-graphite coated electrode that can be replaced when fouling occurs. This approach is more economical than maintaining and regenerating expensive conventional electrodes, achieving cost-effective solution for electrodes that experience fouling

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Measurement precision

If conventional electrodes are used for chlorine species detection, then basic detection is achieved, but environmental interferences affect performance

Engineering Contradiction:
Improvedetection accuracyVSAvoidenvironmental interferences
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent changes the electrochemical parameters of the electrode by using pseudo-graphite material, which provides superior resistance to environmental interferences such as dissolved oxygen and other species. This parameter change enables accurate detection of chlorine species even in complex environmental conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The pseudo-graphite coating acts as an intermediary layer between the electrode substrate and the sample solution. This intermediary provides a stable platform that is insensitive to environmental interferences while maintaining high sensitivity to chlorine species detection

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The pseudo-graphite electrodes provide fast heterogeneous electron transfer and corrosion resistance, enabling effective detection of chlorine species with improved sensitivity and stability, reducing costs and interference issues.

Implementation Method 1

The pseudo-graphite may have fast heterogeneous electron transfer at a basal plane

Methodology Applied
Scientific EffectHeterogeneous electron transfer: Electron Paramagnetic Resonance

Implementation Method 2

The pseudo-graphite may have a corrosion resistance greater than graphitic materials

Methodology Applied
Scientific EffectCorrosion resistance:

Implementation Method 3

The amine groups may be added to the pseudo-graphite surface by a Kolbe electro-oxidation of a carbamate group

Methodology Applied
Scientific EffectKolbe electro-oxidation: Oxidation

Implementation Method 4

The method may include modifying the pseudo-graphite surface with gold nanoparticles

Methodology Applied
Scientific EffectNanoparticle grafting: Adsorption

Data Source

PatentUS11585776B2Chlorine species sensing using pseudo-graphite
Publication Date: 2023.02.21 ABB (SCHWEIZ) AG
  • US11585776B2 patent drawing
  • US11585776B2 patent drawing
  • US11585776B2 patent drawing

AI summary

Methods, electrodes, and sensors for chlorine species sensing using pseudo-graphite are disclosed. In one illustrative embodiment, a method may include coating a pseudo-graphite material onto a surface of an electrode substrate to produce a pseudo-graphite surface. The method may also include exposing the pseudo-graphite surface to a sample to detect chlorine species in the sample.