Pseudo-Isothermal Methanol Reactor Cooling System

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Pseudo-isothermal reactors are expensive and complex, limiting their use due to the need for multiple inlets and outlets, large exterior surfaces, and the complication of coupling steam circuits, which increases costs and restricts the use of multiple stages in processes like methanol and methane production.

Innovation Solution

Configuring a single pseudo-isothermal reactor shell with multiple reaction stages sharing a single cooling medium enclosure and circuit, allowing independent operation of each stage while maintaining a constant cooling medium temperature, thus reducing capital costs and simplifying the design.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If multiple pseudo-isothermal reactors are used to achieve optimal two-stage isothermal operation, then reaction efficiency and equilibrium favorability are improved, but capital costs and device complexity increase significantly

Engineering Contradiction:
Improvereaction efficiencyVSAvoiddevice complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent combines multiple reaction enclosures within a single reactor shell that shares a common cooling medium enclosure and circuit. This merging approach allows multiple reaction stages to operate simultaneously with independent temperature control, achieving the productivity benefits of multi-reactor systems while eliminating the complexity and cost of coupling multiple steam circuits.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The reactor is divided into multiple reaction enclosures (first and second reaction enclosures) that can be independently configured with different catalysts and operating conditions. Each reaction enclosure maintains pseudo-isothermal conditions through the shared cooling system, enabling segment-specific optimization while using a unified cooling infrastructure.

Inventive Principle:
Principle #1Segmentation

2Temperature

If multiple pseudo-isothermal reactors with coupled steam circuits are used, then optimal temperature control is achieved, but operation complexity and costs increase

Engineering Contradiction:
Improvetemperature controlVSAvoidease of operation
Core Design Contradiction:
TemperatureVSEase of operation

Solution Approach 1:

Multiple reaction enclosures share a single cooling medium enclosure and common steam circuit, eliminating the need to couple separate steam circuits. This merging of cooling infrastructure simplifies operation while maintaining independent temperature control in each reaction enclosure through the shared pseudo-isothermal cooling system.

Inventive Principle:
Principle #5Merging (Combining)

3Device complexity

If a single pseudo-isothermal reactor is used to reduce capital costs, then equipment costs are reduced, but the ability to achieve optimal two-stage operation is limited

Engineering Contradiction:
Improveequipment costsVSAvoidreaction efficiency
Core Design Contradiction:
Device complexityVSProductivity

Solution Approach 1:

The patent merges multiple reaction enclosures within a single reactor shell, achieving the cost benefits of a single reactor while maintaining the productivity advantages of multi-stage operation. The shared cooling medium enclosure and steam circuit reduce equipment costs compared to multiple separate reactors, while independent reaction enclosures enable optimal two-stage operation with different catalysts and conditions.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

Within the single reactor shell, the reaction space is segmented into multiple reaction enclosures that can operate independently with different catalysts and operating parameters. This segmentation enables optimal multi-stage reaction performance while the unified cooling system keeps equipment costs lower than using separate reactors.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This configuration significantly reduces capital costs and simplifies the design of pseudo-isothermal reactors, enabling efficient operation of multiple stages with a single cooling medium enclosure and circuit, enhancing the production of methanol and other exothermal equilibrium-limited processes.

Implementation Method 1

a cooling medium enclosure configured to hold a cooling medium under pressure at a temperature proximate to the boiling point of said cooling medium, said reaction enclosures having an outer surface configured to be in thermal contact with the cooling medium

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

The pressure on the cooling side controls the boiling point of the cooling medium, which then when operating at the boiling point may act as a heat sink at substantially constant temperature to the extent that liquid water is present in the reactor

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 3

The pressure on the cooling side controls the boiling point of the cooling medium, which then when operating at the boiling point may act as a heat sink

Methodology Applied
Scientific EffectBoiling: Boiling

Data Source

PatentEP3848114A1Process and pseudo-isothermal reactor for production of methanol
Publication Date: 2021.07.14 HALDOR TOPSOE AS
  • EP3848114A1 patent drawingFigure 1
  • EP3848114A1 patent drawingFigure 2~2D
  • EP3848114A1 patent drawingFigure 3

AI summary

The present disclosure relates to a process and a process plant for production of methanol in a pseudo-isothermal flow reactor for comprising at least two reaction enclosures and a cooling medium enclosure configured to hold a cooling medium under pressure at a temperature proximate to the boiling point of said cooling medium, said reaction enclosures having an outer surface configured to be in thermal contact with the cooling medium, and each of said reaction enclosures having an inlet and an outlet with the associated benefit of enabling a two-stage pseudo-isothermal operation while only requiring a single cooling medium enclosure and only single cooling medium circuit.