Two-Step PSG Deposition Reducing Flower Pattern Size

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Solution Overview

Problem

The existing high-density plasma chemical vapor deposition (HDP CVD) process for forming phosphosilicate glass (PSG) at the 130 nm technology node and below is prone to forming flower-shaped crusts, known as 'flower patterns,' which can lead to instability and variability in device performance due to non-uniform phosphorus concentration and etching issues.

Innovation Solution

A two-step deposition method using HDP CVD with modified sputtering deposition ratios, where the first PSG layer has a sputtering deposition ratio of 0.10 to 0.16 and the second layer has a ratio of 0.18 to 0.22, with the first layer contributing 5-30% and the second layer contributing 70-95% to the total thickness, respectively, to control and minimize flower pattern size.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If a single-step HDP CVD process is used to deposit PSG, then the deposition process is simple and fast, but flower-shaped crusts form with non-uniform phosphorus concentration

Engineering Contradiction:
Improvedeposition speedVSAvoidphosphorus concentration uniformity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The single-step deposition process is divided into two sequential steps with different sputtering deposition ratios. The first step uses a lower ratio (0.10-0.16) to deposit an initial PSG layer with controlled phosphorus concentration, while the second step uses a higher ratio (0.18-0.22) to complete the deposition. This segmentation eliminates flower pattern formation while maintaining overall deposition efficiency and achieves uniform phosphorus concentration throughout the PSG layer.

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If helium is used as sputtering gas in HDP CVD, then gap-fill requirements are met, but flower patterns are formed over pattern areas

Engineering Contradiction:
Improvegap-fill qualityVSAvoidflower pattern formation
Core Design Contradiction:
Manufacturing precisionVSObject-generated harmful factors

Solution Approach 1:

The sputtering deposition ratio parameter is changed between two deposition steps. The first step uses a lower ratio (0.10-0.16) that prevents excessive phosphorus accumulation and flower pattern formation, while the second step uses a higher ratio (0.18-0.22) to achieve the required gap-fill quality. This dynamic parameter adjustment maintains both gap-fill performance and pattern area integrity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method reduces flower pattern size by approximately 50% in height and 30% in crust thickness, preventing clipping and sidewall voids, thereby enhancing phosphorus concentration uniformity and etching uniformity.

Implementation Method 1

high-density plasma chemical vapor deposition (HDP CVD)

Methodology Applied
Scientific EffectChemical Vapour Deposition: Chemical Vapour Deposition

Implementation Method 2

high-density plasma chemical vapor deposition (HDP CVD)

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 3

modified sputtering deposition ratios

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS9150963B2Method for depositing phosphosilicate glass
Publication Date: 2015.10.06 SHANGHAI HUALI MICROELECTRONICS CORP
  • US9150963B2 patent drawing
  • US9150963B2 patent drawing
  • US9150963B2 patent drawing

AI summary

A method of depositing phosphosilicate glass (PSG) is disclosed. The method includes a first deposition step for depositing a first PSG layer with a sputtering deposition ratio of 0.10 to 0.16, and a second deposition step for depositing a second PSG layer with a sputtering deposition ratio of 0.18 to 0.22 after the first deposition step. The first PSG layer has a thickness smaller than that of the second PSG layer. With such two-step deposition method, flower pattern having a dramatically reduced size can be formed without occurrence of clipping or formation of sidewall voids in the resultant gate patterns. Specifically, the formed flower pattern has a height reduced by about 50% and a thickness reduced by about 30%.