Pt-Xanthene Bromide Complex for Low-Yield Hydroformylation

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Solution Overview

Problem

Existing Pt(Xantphos)Cl₂ complexes are not efficient in catalyzing hydroformylation reactions, leading to suboptimal yields.

Innovation Solution

A new complex comprising Pt, a ligand of formula (I) with R1, R2, R3, R4, R5, R6, R7, R8 groups selected from H, C1-C12 alkyl, C6-C20 aryl, and a bromine ligand, is used to enhance catalytic efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If Pt(Xantphos)Cl2 complex is used for hydroformylation catalysis, then the reaction can proceed, but the yield is suboptimal

Engineering Contradiction:
ImproveyieldVSAvoidcatalytic efficiency
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the complex by replacing chloride ligands with bromide ligands and modifying the phosphine ligand structure (adding alkyl and aryl groups at positions R1-R8). This parameter change in the complex composition transforms the catalytic properties, increasing both yield and efficiency in hydroformylation reactions compared to the original Pt(Xantphos)Cl2 complex.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If Pt(Xantphos)Cl2 complex is used, then the structure is simple and well-defined, but the catalytic performance is insufficient

Engineering Contradiction:
ImproveyieldVSAvoidcomplex structure
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent creates a composite complex structure by combining Pt center, modified Xantphos ligand with various R groups (R1-R8), and bromide ligands. This composite approach integrates multiple components with different functions: the Pt provides catalytic activity, the modified Xantphos provides structural framework and electronic properties, and the bromide ligands enhance catalytic performance. The resulting composite complex achieves superior yield while maintaining a well-defined structure.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The new complex significantly increases the yield in hydroformylation reactions compared to Pt(Xantphos)Cl₂, achieving up to 99% yield in certain conditions.

Implementation Method 1

the use of Pt(Xantphos)Cl 2 for the hydroformylation of 2-tosyloxystyrene is described

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentEP4198000B1Pt-xanthene-bromine complex
Publication Date: 2026.02.04 EVONIK OXENO GMBH & CO KG
  • EP4198000B1 patent drawing
  • EP4198000B1 patent drawing
  • EP4198000B1 patent drawing

AI summary

Pt-xanthene-bromine complex, and its use for catalyzing a hydroformylation reaction.