PTFE Catalyst Filter Fibers Using Solid-State Mixing

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Solution Overview

Problem

Existing PTFE fibers used in catalyst filters face issues with catalyst desorption during the dedusting process due to their hydrophobic nature, leading to inefficient NOx removal, and conventional SCR processes using vanadium oxides require organic solvents for coating, which complicates the manufacturing process.

Innovation Solution

A method involving the mixing of PTFE powder with a denitrification catalyst comprising V2O5 and a promoter supported on a zeolite substrate, followed by extrusion, rolling, and stretching to create PTFE fibers with uniformly distributed catalyst particles, enhancing catalyst retention and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional SCR process uses vanadium oxides for catalyst coating, then NOx removal performance is achieved, but organic solvents are required which complicates the manufacturing process

Engineering Contradiction:
ImproveNOx removal performanceVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention changes the physical state of the catalyst from liquid coating (requiring organic solvents) to solid particle mixing. The catalyst is prepared as solid particles containing V2O5 and promoters, then mixed with PTFE powder in a solid-state process, eliminating the need for organic solvent-based coating operations.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention replaces the chemical coating process (using organic solvents) with a mechanical mixing process. Solid catalyst particles are mixed with PTFE powder through mechanical means (mixing equipment), then the mixture is extruded and formed into fibers, substituting the chemical coating step with a mechanical mixing and forming step.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If PTFE fibers are used as catalyst filter media, then filter performance is achieved, but catalyst particles are desorbed during dedusting process

Engineering Contradiction:
Improvefilter performanceVSAvoidcatalyst desorption
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The invention merges the catalyst particles with the PTFE fiber formation process. Catalyst particles are mixed with PTFE powder before extrusion, so the catalyst becomes an integral part of the fiber structure rather than a separate coating. This merging prevents catalyst desorption during subsequent dedusting operations.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention performs preliminary mixing of catalyst particles with PTFE powder before the extrusion and fiber formation process. This preliminary action ensures that catalyst particles are distributed throughout the PTFE matrix in advance, preventing them from being desorbed or lost during later dedusting operations.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If catalyst is coated on PTFE surface, then denitrification performance is imparted, but catalyst desorption occurs during lamination process

Engineering Contradiction:
Improvedenitrification performanceVSAvoidcatalyst desorption during lamination
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The invention merges the catalyst with the PTFE fiber structure through mixing before extrusion, rather than coating it on the surface. This integration ensures that during the lamination process, the catalyst remains bound within the fiber matrix and does not desorb, maintaining denitrification performance.

Inventive Principle:
Principle #5Merging (Combining)

4Ease of manufacture

If organic solvents are used for catalyst coating, then catalyst application is achieved, but manufacturing efficiency is reduced

Engineering Contradiction:
Improvecatalyst applicationVSAvoidmanufacturing efficiency
Core Design Contradiction:
Ease of manufactureVSProductivity

Solution Approach 1:

The invention replaces the chemical coating process using organic solvents with a mechanical mixing process. Solid catalyst particles are mixed with PTFE powder through mechanical mixing equipment, then the mixture is extruded continuously. This mechanical approach eliminates solvent evaporation steps and simplifies the manufacturing process, improving overall efficiency.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method results in a more efficient denitrification catalyst with improved NOx removal performance and reduced catalyst desorption, while allowing for uniform catalyst application and increased filter productivity through optimized drying processes.

Implementation Method 1

catalytic reduction of nitrogen oxides has been used to reduce NOx in exhaust gas

Methodology Applied
Scientific EffectCatalytic reduction: Catalysis

Implementation Method 2

a catalytic reduction process is also called a selective catalytic reduction process, diminishingly SCR (Selective Catalytic Reduction) process

Methodology Applied
Scientific EffectSelective catalytic reduction: Catalysis

Implementation Method 3

PTFE fibers are hydrophobic fluorine polymer fibers, so there is a problem that an organic solvent should be used for catalyst coating

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS20250214073A1Method for manufacturing high-efficiency denitration catalysts, method for modifying the surface of PTFE fibers by mixing solid particles, and method for manufacturing PTFE catalyst filter
Publication Date: 2025.07.03 MICRO ONE CO LTD
  • US20250214073A1 patent drawing
  • US20250214073A1 patent drawing
  • US20250214073A1 patent drawing

AI summary

Disclosed are a method of manufacturing a high-efficiency denitrification catalyst by adjusting components constituting a denitrification catalyst and a ratio between respective components, a method of modifying the surface of PTFE fibers by extruding, rolling, stretching and slitting a PTFE billet manufactured using mixed solid particles, and a method of producing a PTFE catalyst filter by the methods.