PTFE Membrane Gradient Pore Structure for Filtration Trade-offs

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Solution Overview

Problem

Existing PTFE filtration membranes struggle to achieve a balance between high filtration precision and low flow resistance, often requiring trade-offs between pore size, permeability, and mechanical strength.

Innovation Solution

A PTFE membrane with a gradient pore structure is developed, featuring a first porous outer surface with an island-like microstructure and a second porous outer surface with an H-shaped ladder-like microstructure, optimized through a specific method involving isoalkane mixing, extrusion, and controlled stretching.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If the pore size of the filtration material is reduced to achieve high filtration precision, then the filtration precision is improved, but the permeability of liquids or gases through the membrane is reduced

Engineering Contradiction:
Improvefiltration precisionVSAvoidpermeability
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent applies local quality by creating different pore structures at different locations within the membrane. The surface layer contains smaller pores for high filtration precision, while the inner layer contains larger pores for high permeability. This spatial differentiation of pore sizes allows each layer to perform its specific function optimally without compromising the other.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The membrane is segmented into distinct layers with different pore characteristics. The surface layer is separated from the inner layer, with the surface layer providing filtration function and the inner layer providing support and flow capacity. This segmentation allows independent optimization of each layer's pore structure to resolve the contradiction between filtration precision and permeability.

Inventive Principle:
Principle #1Segmentation

2Productivity

If the pore size of the filtration material is increased to enhance membrane flow capacity, then the permeability is improved, but the number of captured particles is reduced, thus reducing filtration efficiency

Engineering Contradiction:
Improvemembrane flow capacityVSAvoidfiltration efficiency
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

Different regions of the membrane have different pore sizes optimized for their specific functions. The surface layer has smaller pores arranged to maximize particle capture, while the inner layer has larger pores to maximize flow capacity. This local optimization ensures that each region contributes to resolving the contradiction between flow capacity and filtration efficiency.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The membrane exhibits asymmetric pore structure with a distinct surface layer and inner layer. The surface layer has a different pore size distribution compared to the inner layer, creating an asymmetric structure that optimizes both filtration efficiency and flow capacity simultaneously, rather than using a uniform pore structure throughout.

Inventive Principle:
Principle #4Asymmetry

3Productivity

If the thickness of the filtration material is reduced to improve filtration rates, then the filtration rate is improved, but the mechanical strength of the membrane is weakened

Engineering Contradiction:
Improvefiltration rateVSAvoidmechanical strength
Core Design Contradiction:
ProductivityVSStrength

Solution Approach 1:

The membrane is divided into functional segments where the surface layer (thinner) provides filtration and the inner layer (thicker) provides structural support. This segmentation allows the overall membrane to achieve high filtration rates through the thin surface layer while maintaining mechanical strength through the thicker supporting inner layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The inner layer serves multiple functions: it provides mechanical strength to the membrane structure and simultaneously acts as a flow channel with large pores to maintain high permeability. This multi-functionality allows the membrane to achieve both high filtration rate and adequate mechanical strength without simply increasing overall thickness.

Inventive Principle:
Principle #6Universality (Multi-functionality)

4Productivity

If the count of pores per unit area is significantly increased to increase processing volume, then the processing capacity is improved, but it is extremely challenging to implement under specific production conditions

Engineering Contradiction:
Improveprocessing capacityVSAvoidmanufacturing feasibility
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

Instead of uniformly increasing pore count across the entire membrane (which is manufacturingally difficult), the patent creates a high pore count in the surface layer where it is most needed for filtration, while the inner layer has fewer but larger pores. This local differentiation achieves high processing capacity without requiring extreme pore counts throughout the entire membrane thickness, making it more manufacturable.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The PTFE membrane with a gradient pore structure maintains low resistance and high flow rates while preserving filtration accuracy, enhancing contaminant capture efficiency and reducing energy costs.

Implementation Method 1

the PTFE membrane with a gradient pore structure combines the characteristics of low flow resistance and small pore size, making it excellent in terms of filtration rate and reliable retention accuracy for both liquid and gas filtration

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 2

Expanded polytetrafluoroethylene (hereinafter referred to as PTFE) membranes with a porous structure have found widespread application in the fields of liquid and gas filtration

Methodology Applied
Scientific EffectPhysical filtration: Filter (physical)

Data Source

PatentUS20250135408A1Polytetrafluoroethylene (PTFE) membranes with gradient pore structures and methods for preparing the same
Publication Date: 2025.05.01 FEATURE TEC (SHANGHAI) ADVANCED MATERIALS CO LTD
  • US20250135408A1 patent drawing
  • US20250135408A1 patent drawing
  • US20250135408A1 patent drawing

AI summary

A polytetrafluoroethylene (PTFE) membrane with a gradient pore structure and a method for preparing the same are disclosed. A cross-section of the PTFE membrane has the gradient pore structure, and a first porous outer surface and a second porous outer surface of the PTFE membrane have fibers and nodes with different microstructures. The first porous outer surface has an island-like microstructure formed by a plurality of interconnected relatively-small nodes, and the second porous outer surface has an H-shaped ladder-like microstructure formed by a plurality of interconnected relatively-large nodes. The PTFE membrane produced by this method features low resistance and high flow rate while maintaining thickness and filtration precision. The improvement in filtration efficiency enhances the capture of contaminants. For a given transmembrane pressure drop, the high permeability or high flow capacity of the membrane reduces resistance loss, shortens filtration time, and thus reduces energy costs.