Porous PTFE Membrane Liquid-Repellent Coating for Waterproof Sound Transmission

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Solution Overview

Problem

Conventional gas-permeable membranes with liquid repellency are prone to wrinkling and sagging when cut and integrated into electronic device housings, leading to reduced sound transmission.

Innovation Solution

A porous PTFE membrane coated with a liquid-repellent agent obtained by polymerizing monomers consisting of CH2═CHCOOCH2CH2C6F13, which allows for stretching and reduces deformation, combined with a method involving forming, stretching, and liquid-repellent treatment steps to enhance flexibility and prevent wrinkling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a conventional gas-permeable membrane with liquid repellency is used, then liquid repellency is achieved, but the membrane is prone to wrinkling and sagging when cut and integrated into housings

Engineering Contradiction:
Improveliquid repellencyVSAvoidmembrane shape stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent changes the chemical composition parameters of the liquid-repellent agent by using a fluorine-containing polymer with specific molecular weight (10,000 to 1,000,000) and fluorine content (50 to 90 mass%), which optimizes both liquid repellency and flexibility to prevent wrinkling and sagging

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by coating the porous PTFE membrane with a fluorine-containing polymer liquid-repellent agent, combining the gas permeability of PTFE with the liquid repellency and flexibility enhancement from the fluorine polymer

Inventive Principle:
Principle #40Composite materials

2Stability of the object's composition

If the membrane is stretched to reduce wrinkling, then shape stability improves, but liquid repellency may be compromised

Engineering Contradiction:
Improvemembrane shape stabilityVSAvoidliquid repellency
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent optimizes the physical parameters of the liquid-repellent agent including molecular weight (10,000 to 1,000,000) and fluorine content (50 to 90 mass%) to ensure that the coating maintains liquid repellency even after the membrane is stretched during integration

Inventive Principle:
Principle #35Parameter changes

3Object-generated harmful factors

If a thin membrane is used for good sound transmission, then sound transmission improves, but the membrane becomes more susceptible to deformation

Engineering Contradiction:
Improvesound transmission qualityVSAvoidmembrane strength
Core Design Contradiction:
Object-generated harmful factorsVSStrength

Solution Approach 1:

The patent changes the mechanical properties of the thin membrane by coating it with a fluorine-containing polymer that enhances flexibility and reduces deformation, allowing the membrane to remain thin for good sound transmission while resisting deformation during cutting and integration

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The membrane achieves sufficient liquid repellency and reduced wrinkling and sagging, maintaining sound pressure loss of 2.0 dB or less and elongation at break between 200 to 600%, ensuring effective sound transmission and waterproofing.

Implementation Method 1

Even if a highly water-repellent porous PTFE membrane is used as a gas-permeable membrane, entry of a liquid with a low surface tension cannot be fully prevented

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Implementation Method 2

a gas-permeable membrane having a porous polytetrafluoroethylene (PTFE) membrane is suitable... imparted with liquid repellency

Methodology Applied
Scientific EffectHydrophobic effect: Hydrophobe

Implementation Method 3

a gas-permeable membrane that allows passage of gasses but prevents entry of water

Methodology Applied
Scientific EffectPermeation: Permeation

Implementation Method 4

a gas-permeable membrane having a porous polytetrafluoroethylene (PTFE) membrane

Methodology Applied
Scientific EffectPorosity: Porosity

Implementation Method 5

Rf groups having 8 or more carbon atoms have significantly higher crystallinity than Rf groups having a smaller number of carbon atoms... The receding contact angle increases with increasing crystallinity

Methodology Applied
Scientific EffectSurface energy reduction: Surface Tension

Data Source

PatentUS9630150B2Porous polytetrafluoroethylene membrane, method for producing the same, gas-permeable membrane and ventilation member using the same
Publication Date: 2017.04.25 NITTO DENKO CORP
  • US9630150B2 patent drawing
  • US9630150B2 patent drawing
  • US9630150B2 patent drawing

AI summary

The present invention provides a porous polytetrafluoroethylene membrane having a surface coated with a liquid-repellent agent. In this porous polytetrafluoroethylene membrane, the liquid-repellent agent is a polymer obtained by polymerization of monomers consisting essentially of CH2═CHCOOCH2CH2C6F13. This porous polytetrafluoroethylene membrane is suitable for use as a gas-permeable membrane that allows passage of gases but prevents entry of liquids and/or dust, specifically as a waterproof sound-transmitting membrane, a waterproof gas-permeable membrane, or a dustproof gas-permeable membrane.