PTFE Membrane Micro-Eutectic Treatment for Ice Prevention

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Solution Overview

Problem

Current methods for preventing and removing ice from wind turbine blades are inefficient, particularly those using resistance wires and electrothermal systems, which increase weight and power consumption, and fail to effectively prevent ice adhesion due to low surface tension and lubricating properties of PTFE materials.

Innovation Solution

A high-temperature high-linear-pressure micro-eutectic method is applied to a PTFE-based membrane, creating a nano functional composite membrane with enhanced structural strength, abrasion resistance, and impact resistance by arranging micro-eutectic molecular structures in parallel, resulting in a transparent, ultra-micro structured surface with improved adhesion resistance and ice prevention capabilities.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If resistance wires and electrothermal systems are used to prevent ice adhesion, then ice prevention capability is improved, but weight and power consumption increase

Engineering Contradiction:
Improveice prevention capabilityVSAvoidweight
Core Design Contradiction:
ReliabilityVSWeight of moving object

Solution Approach 1:

The patent replaces the mechanical/electrical heating system (resistance wires, electrothermal systems) with a surface chemistry-based solution. By modifying the surface properties of the membrane through high-temperature high-linear-pressure micro-eutectic treatment, the surface achieves inherent ice resistance without requiring external heating systems, thus eliminating the weight and power consumption issues associated with electrothermal systems

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The treated membrane surface possesses inherent ice-resistant properties that enable it to prevent ice adhesion autonomously without requiring external energy input or active control systems. The micro-eutectic treatment creates a surface structure and chemistry that naturally resists ice accumulation, making the system self-sufficient and eliminating the need for continuous power consumption

Inventive Principle:
Principle #25Self-service

2Ease of operation

If PTFE-based membrane is used for ice prevention, then lubricating properties are improved, but ice adhesion resistance is insufficient

Engineering Contradiction:
Improvelubricating propertiesVSAvoidice adhesion resistance
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent applies high-temperature high-linear-pressure micro-eutectic treatment to fundamentally change the physical and chemical parameters of the PTFE-based membrane surface. This treatment modifies the surface energy, creates micro-eutectic structures, and alters the surface morphology, transforming the surface properties to achieve both lubrication and enhanced ice adhesion resistance simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure at the micro-scale by forming micro-eutectic phases within the PTFE-based membrane. This micro-composite structure combines different crystalline phases and amorphous regions in a controlled manner, creating a surface that exhibits both the lubricating properties of PTFE and enhanced resistance to ice adhesion through the micro-eutectic architecture

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If conventional membrane treatment is applied, then manufacturing simplicity is maintained, but structural strength and abrasion resistance are insufficient

Engineering Contradiction:
Improvemanufacturing simplicityVSAvoidstructural strength and abrasion resistance
Core Design Contradiction:
Ease of manufactureVSStrength

Solution Approach 1:

The patent utilizes phase transition phenomena during the high-temperature high-linear-pressure treatment process. The membrane undergoes crystallization and micro-eutectic formation as it is heated and pressed, transforming its molecular structure to create a denser, stronger, and more abrasion-resistant structure. This phase transition occurs in-situ during the treatment process, maintaining manufacturing simplicity while dramatically improving mechanical properties

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method significantly enhances the integral structural strength and abrasion resistance of the PTFE-based membrane, effectively preventing ice adhesion and improving the blade's surface strength, erosion resistance, and longevity, while reducing the risk of aging and cracking.

Implementation Method 1

enabling membrane molecular chains to shrink and generate eutectic phases, wherein multiple micro-eutectic molecular structures are arranged in parallel

Methodology Applied
Scientific EffectMicro-eutectic formation:

Implementation Method 2

micro-pores between the membrane molecular chains become nano-scale and ultra-micron-scale

Methodology Applied
Scientific EffectPore formation: Porosity

Implementation Method 3

the color of the membrane after the micro-eutectic changes from opaque milky white to transparent color with high and uniform transparency

Methodology Applied
Scientific EffectThermal processing: Heat Treatment

Data Source

PatentUS12138871B2High-temperature high-linear-pressure micro-eutectic method for enhancing strength of polytetrafluoroethylene (PTFE)-based membrane
Publication Date: 2024.11.12 CHINA THREE GORGES CORPORATION

AI summary

A high-temperature high-linear-pressure micro-eutectic method for enhancing a strength of a polytetrafluoroethylene (PTFE)-based membrane is disclosed. The method comprises the following steps: pushing a PTFE-based nano functional composite membrane forwards at a speed of 6-8 m/min in a high-temperature high-linear-pressure micro-eutectic cavity with a length of 1.5 m at a temperature of 380° C., controlling a linear pressure of a surface of the PTFE-based membrane to be 50-80 N/m, and under a coiling traction of a membrane coiling roller outside the cavity, enabling membrane molecular chains to shrink and generate eutectic phases, wherein multiple micro-eutectic molecular structures are arranged in parallel, and the PTFE-based nano functional composite membrane has a density of 2.1 kg/m3 and has nanoscale macromolecular aggregates and a nano-scale and micron-scale concave-convex geometrical ultra-micro-structure morphology with a surface average size of 10-20 μm, a height of 5-10 μm and a spacing of 10-20 km.