PTFE/PFPE Composite Particles for Homogeneous Polymer Dispersion

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Solution Overview

Problem

The use of fluoropolymer additives like PFPE and PTFE in polymers faces challenges such as high cost, difficulty in homogeneous dosing and dispersion, and reduction in mechanical properties at high concentrations, especially with PTFE powder requiring significant amounts to achieve desired effects.

Innovation Solution

Combining PFPE polymer with micronized PTFE particles in specific weight ratios to create PTFE/PFPE particles, which absorb PFPE into the PTFE, improving dosing and dispersion, and enhancing properties like friction reduction and wear resistance without compromising mechanical strength.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If small amounts of PFPE (about 0.1 weight percent) are added to polymer to reduce friction and wear, then cost is reduced and economically attractive product is produced, but homogeneous dosing and dispersion becomes difficult in standard processing equipment

Engineering Contradiction:
Improveamount of PFPE additiveVSAvoidhomogeneous dosing and dispersion
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The patent combines PFPE polymer with PTFE powder to create a composite additive system. The PTFE serves as a carrier matrix that incorporates the PFPE, allowing the low-cost PFPE to be delivered in sufficient quantities while the PTFE provides the necessary handling and dispersion properties. This composite approach resolves the contradiction by enabling both economical dosing and homogeneous distribution.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

PTFE acts as an intermediary carrier material that facilitates the dosing and dispersion of PFPE. The PTFE powder provides a bulk matrix that makes the low-concentration PFPE easier to handle, dose homogeneously, and disperse in standard processing equipment, while still delivering the friction and wear reduction benefits of the PFPE.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If high concentrations of PTFE powder (above 5 weight percent) are added to polymer to improve friction coefficient and wear rate, then significant desired effects are obtained, but mechanical properties such as impact and tensile strength are reduced

Engineering Contradiction:
Improvefriction coefficient and wear rate improvementVSAvoidimpact and tensile strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent uses a small amount of PFPE (the effective functional component) incorporated into a larger PTFE matrix. The PFPE provides the friction and wear protection at low concentrations (avoiding the strength reduction problem of high PTFE loading), while the PTFE carrier provides the necessary bulk and handling properties. This allows achieving reliability benefits without the strength penalty of high additive concentrations.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Reliability

If PTFE powder is used as additive to improve friction and wear properties, then desired lubrication effects are achieved, but relatively high concentrations (above 5 weight percent) are needed which reduces mechanical properties

Engineering Contradiction:
Improvefriction and wear protectionVSAvoidconcentration of additive
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent merges PFPE polymer with PTFE powder to create a combined additive system. The PFPE provides superior friction and wear protection at low concentrations, while the PTFE provides bulk and handling properties. This combination allows achieving the same or better lubrication effects at lower total additive concentrations compared to using PTFE alone, thereby preserving mechanical properties.

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The PTFE/PFPE particles provide an economical and effective additive that ensures homogeneous distribution and improved properties in polymers, such as reduced friction and wear, while maintaining or improving mechanical strength, even at lower concentrations.

Implementation Method 1

the PFPE is absorbed into the PTFE which modifies certain properties of the PTFE particles

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS10087290B2Particles comprising polytetrafluoroethylene and perfluoropolyether
Publication Date: 2018.10.02 THE CHEMOURS CO FC LLC

AI summary

Novel PTFE/PFPE particles and method for making the same are disclosed. The PFPE is absorbed into the PTFE particles. The PTFE/PFPE particles find utility as additives to be combined with other polymers.