P-Type CZT Detector Doping for High-Flux Polarization Resistance

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Solution Overview

Problem

Photon counting X-ray computed tomography (CT) imaging systems experience performance loss due to electrical polarization during high-flux applications, which affects the detector's ability to accurately count X-ray photons at high flux rates.

Innovation Solution

An ionizing radiation detector with a p-type semiconductor single crystal substrate doped with n-type dopant atoms, where the concentration of deep level acceptor defects exceeds that of n-type dopant atoms, preventing detector polarization by maintaining a stable electric field under high X-ray flux conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional charge sensitive amplifier systems are used for photon counting X-ray CT, then the system can operate at standard flux rates, but performance is lost during high-flux applications due to electrical polarization

Engineering Contradiction:
Improvedetector performance stabilityVSAvoidX-ray flux handling capacity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent changes the electrical parameters of the detector by introducing a p-type layer with specific hole concentration (10^16 to 10^18 cm^-3) and controlling the doping concentration (10^14 to 10^16 cm^-3). This parameter modification enables the detector to maintain stable performance under high-flux conditions by preventing charge accumulation that causes polarization.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite semiconductor structure by combining n-type CZT material with a p-type layer. This composite structure leverages the complementary properties of both material types: the n-type material provides good charge transport while the p-type layer with controlled doping prevents polarization, achieving both high flux handling and performance stability.

Inventive Principle:
Principle #40Composite materials

2Productivity

If the detector is designed to handle high X-ray flux rates, then productivity increases, but electrical polarization occurs causing loss of measurement precision

Engineering Contradiction:
ImproveX-ray photon counting rateVSAvoidphoton counting accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent modifies the electrical parameters of the detector by introducing a p-type layer with specific hole concentration (10^16 to 10^18 cm^-3) and controlling the doping concentration (10^14 to 10^16 cm^-3). This parameter modification enables the detector to maintain stable performance under high-flux conditions by preventing charge accumulation that causes polarization.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potentially harmful effect of high flux-induced charge accumulation into a beneficial effect by using the p-type layer to attract and neutralize excess charges. The high flux that would normally cause polarization is instead managed by the p-type material, allowing accurate photon counting even at high counting rates.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

3Ease of manufacture

If conventional n-type doped CZT substrates are used, then manufacturing is straightforward, but the detector experiences polarization under high-flux conditions

Engineering Contradiction:
Improvesubstrate doping processVSAvoidpolarization resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent creates a composite semiconductor structure by combining n-type CZT material with a p-type layer. This composite structure leverages the complementary properties of both material types: the n-type material provides good charge transport while the p-type layer with controlled doping prevents polarization, achieving both high flux handling and performance stability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies local quality modification by introducing a p-type layer with specific properties (hole concentration 10^16 to 10^18 cm^-3) at a specific location within the detector structure. This localized modification with controlled doping concentration (10^14 to 10^16 cm^-3) provides polarization resistance exactly where needed without compromising the overall detector performance or manufacturing feasibility.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The detector operates effectively at high X-ray flux rates without experiencing polarization, ensuring accurate photon counting and maintaining performance across a wide range of X-ray flux conditions.

Implementation Method 1

a concentration of deep level acceptor defects is greater than a concentration of the n-type dopant atoms in the p-type semiconductor single crystal substrate

Methodology Applied
Scientific EffectElectrical polarization prevention through deep level acceptor defects:

Implementation Method 2

the charge cloud resulting from an X-ray photon impinging on a sensor is converted to an amplified voltage

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Data Source

PatentUS12094988B1P-type CZT radiation detector for high flux applications
Publication Date: 2024.09.17 REDLEN TECH
  • US12094988B1 patent drawing
  • US12094988B1 patent drawing
  • US12094988B1 patent drawing

AI summary

An ionizing radiation detector includes a p-type semiconductor single crystal substrate having first and second major planar opposing surfaces, where the p-type semiconductor single crystal substrate is doped with n-type dopant atoms, and where a concentration of deep level acceptor defects is greater than a concentration of the n-type dopant atoms in the p-type semiconductor single crystal substrate; a cathode electrode on the first major planar opposing surface of the p-type semiconductor single crystal substrate, and a plurality of anode electrodes on the second major planar opposing surface of the p-type semiconductor single crystal substrate.