Pulsed Plasma Analyzer Radical Kinetics Control

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Solution Overview

Problem

The challenge in plasma processes is precisely controlling radical kinetics due to their sensitivity to wall conditions in plasma chambers, which affects the outcome of processes like plasma etching, as existing technologies lack effective methods for accurately analyzing and managing radical concentrations and lifetimes.

Innovation Solution

A pulsed plasma analyzer is developed, comprising a pulse modulator, optical spectrometer, and concentration estimating module, which generates pulsed plasma with adjustable pulse levels, measures optical emissions, and estimates radical concentrations and lifetimes based on initial emission values during off-times, allowing for precise control of radical kinetics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If radical kinetics are analyzed in low pressure plasma process, then plasma process control precision is improved, but measurement difficulty increases due to sensitivity to wall conditions

Engineering Contradiction:
Improveradical kinetics measurement precisionVSAvoidradical concentration measurement difficulty
Core Design Contradiction:
Measurement precisionVSDifficulty of detecting and measuring

Solution Approach 1:

The patent applies periodic pulsed plasma generation with alternating on-time and off-time periods. During off-time, radical generation stops while existing radicals decay, creating periodic concentration variations that can be measured. This periodic action transforms the continuous measurement problem into a time-resolved measurement problem, enabling precise radical kinetics analysis through temporal modulation of plasma generation.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent changes the temporal parameters of plasma generation by introducing pulse width modulation with variable on-time and off-time durations. By adjusting these time parameters, the radical concentration can be controlled and optimized for measurement. The off-time parameter specifically allows radical decay to occur, creating measurable concentration changes that reveal kinetic information.

Inventive Principle:
Principle #35Parameter changes

2Ease of operation

If pulsed plasma with adjustable off-time is used, then radical concentration control is improved, but device complexity increases

Engineering Contradiction:
Improveradical concentration control easeVSAvoidpulsed plasma device complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent introduces dynamic control of plasma generation through adjustable pulse parameters. The off-time duration can be dynamically changed to control radical decay extent, providing flexible radical concentration control. This dynamic parameter adjustment transforms a static plasma system into a controllable system where radical kinetics can be precisely managed through temporal parameter variation.

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution enables precise analysis and control of radical kinetics, improving the accuracy and efficiency of plasma processes by providing real-time concentration and lifetime data of target radicals, thereby enhancing process control and outcomes.

Implementation Method 1

an optical spectrometer that measures optical emissions of the pulsed plasma after the off-time and outputs optical emission data

Methodology Applied
Scientific EffectOptical emission: Luminescence

Data Source

PatentUS10249485B2Pulsed plasma analyzer and method for analyzing the same
Publication Date: 2019.04.02 SAMSUNG ELECTRONICS CO LTD
  • US10249485B2 patent drawing
  • US10249485B2 patent drawing
  • US10249485B2 patent drawing

AI summary

A pulsed plasma analyzer includes a pulse modulator that controls an off-time of a pulsed plasma that includes a target radical, an optical spectrometer that measures optical emissions of the pulsed plasma after the off-time to determine optical emission data, and a concentration estimating module that estimates a concentration of the target radical during the off-time based on an initial optical emission value of the optical emission data that changes as a function of the off-time, and outputs an estimated concentration.