Pulsed Remote Plasma Etching for Ion Damage Reduction

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Solution Overview

Problem

Substrate processing systems face challenges in controlling ion exposure during plasma etching, leading to damage and non-uniform etch rates due to the generation of highly reactive ions in continuous wave plasma systems.

Innovation Solution

Implementing a pulsed remote plasma etching method that alternates between ON and OFF periods to control ion energy distribution, with the OFF period duration set based on ion lifetime, reducing ion energy impact while maintaining radical density, thereby minimizing ion charge damage and improving etch rate uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If continuous wave plasma is used to activate chemical reactions, then etching productivity is improved, but ion damage to substrate increases

Engineering Contradiction:
Improveetching productivityVSAvoidion damage
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent applies periodic pulsed plasma generation instead of continuous wave plasma. The plasma is generated in discrete pulses with controlled duration and frequency, allowing the substrate to be exposed to reactive species without continuous ion bombardment. This temporal modulation resolves the contradiction by providing chemical reactivity during plasma ON periods while reducing ion damage through OFF periods between pulses.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent dynamically controls plasma parameters including power level, pulse duration, and duty cycle to optimize the balance between etching productivity and ion damage reduction. By making plasma generation dynamic rather than static, the system can adapt the intensity and duration of plasma exposure to achieve effective etching while minimizing harmful ion effects on the substrate.

Inventive Principle:
Principle #15Dynamics

2Reliability

If continuous wave plasma is used, then chemical reactions are activated, but etch rate uniformity deteriorates

Engineering Contradiction:
Improvechemical reaction activationVSAvoidetch rate uniformity
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

Pulsed plasma generation creates periodic cycles of reactive species formation and depletion. During ON periods, radicals are generated for chemical reactions; during OFF periods, radical density decreases while ion damage is minimized. This periodic modulation improves etch rate uniformity across the substrate by preventing excessive radical accumulation that causes non-uniform etching in continuous wave systems.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent changes key plasma parameters including power level, pressure, gas flow rate, and pulse timing to optimize both chemical reaction activation and etch uniformity. By carefully controlling the duty cycle and pulse width, the system maintains sufficient radical density for effective etching while preventing the conditions that lead to non-uniform etch rates across the substrate surface.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The pulsed remote plasma etching method reduces ion energy and electron temperature during OFF periods, decreasing substrate damage and enhancing etch rate uniformity by maintaining desired radical densities, thus improving the overall performance and reducing the 'W' shape etch rate profile.

Implementation Method 1

supplying, in an ON period, a first voltage to coils arranged around the upper chamber region to energize the at least one gas mixture and generate plasma within the upper chamber region

Methodology Applied
Scientific EffectElectromagnetic induction: Electromagnetic Induction

Implementation Method 2

ICP produces both highly reactive neutral species and ions to modify wafer surfaces

Methodology Applied
Scientific EffectPlasma: Plasma

Implementation Method 3

radio frequency (RF) plasma such as inductively coupled plasma (ICP) may be used to activate chemical reactions

Methodology Applied
Scientific EffectPhotoionisation: Photoionisation

Data Source

PatentUS20230223237A1Pulsing remote plasma for ion damage reduction and etch uniformity improvement
Publication Date: 2023.07.13 LAM RES CORP
  • US20230223237A1 patent drawing
  • US20230223237A1 patent drawing
  • US20230223237A1 patent drawing

AI summary

A method of performing pulsed remote plasma etching includes arranging a substrate in a processing chamber configured to perform pulsed remote plasma etching, setting at least one process parameter of the processing chamber, supplying at least one gas mixture to an upper chamber region of the processing chamber, supplying, in an ON period, a first voltage to coils arranged around the upper chamber region to energize the at least one gas mixture and generate plasma within the upper chamber region of the processing chamber, turning off the first voltage in an OFF period to discontinue generating plasma within the upper chamber region of the processing chamber, and alternating between supplying the first voltage in the ON period and turning off the first voltage in the OFF period to generate pulsed remote plasma within the upper chamber region of the processing chamber.