Pumice-Based Lightweight Cement for Wellbore Void Sealing

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Solution Overview

Problem

Conventional Portland cement-based remedial cementing operations are energy-intensive and costly, with high environmental impact, and recent shortages have exacerbated the rising costs of hydraulic cement compositions.

Innovation Solution

A lightweight settable composition is developed, free of Portland cement, comprising pumice, a calcium activator, and either metakaolin, shale, or zeolite, which is used to seal voids in well bores, offering a cost-effective and environmentally friendlier alternative with fast setting properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If Portland cement-based compositions are used for remedial cementing, then compressive strength and sealing effectiveness are achieved, but energy consumption and environmental impact increase significantly

Engineering Contradiction:
Improvecompressive strengthVSAvoidenergy consumption
Core Design Contradiction:
StrengthVSUse of energy by moving object

Solution Approach 1:

The patent changes the chemical composition parameters by replacing Portland cement with a blend of hydraulic cement and pozzolan materials (fly ash, silica fume, metakaolin) in specific proportions (60-80% hydraulic cement, 20-40% pozzolan). This parameter change maintains compressive strength while reducing energy consumption and environmental impact, as pozzolans require significantly less energy to produce than Portland cement

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite cementitious material by combining hydraulic cement with pozzolan materials that have complementary properties. The hydraulic cement provides initial strength and the pozzolans contribute to long-term durability and strength development through secondary hydration reactions, achieving required compressive strength with lower environmental footprint

Inventive Principle:
Principle #40Composite materials

2Reliability

If Portland cement-based compositions are used for remedial cementing, then adequate sealing performance is achieved, but cost increases due to recent shortages and rising prices

Engineering Contradiction:
Improvesealing performanceVSAvoidcost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent modifies the material composition by incorporating pozzolan materials that are generally more abundant and less subject to shortage volatility than Portland cement. The specific blend ratios (60-80% hydraulic cement, 20-40% pozzolan) optimize both performance and cost-effectiveness, providing adequate sealing performance at lower material costs

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes pozzolan materials such as fly ash and silica fume that are byproducts of other industrial processes, making them cheaper and more readily available than Portland cement. These materials provide sufficient functional performance for remedial cementing applications at reduced cost

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Duration of action of stationary object

If Portland cement-based compositions are used, then setting and hardening occur, but environmental footprint and carbon emissions increase

Engineering Contradiction:
Improvesetting and hardeningVSAvoidenvironmental footprint
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent changes the chemical composition by replacing a portion of Portland cement (20-40%) with pozzolan materials that have lower carbon footprints. The pozzolans undergo secondary hydration reactions that continue after initial setting, providing long-term strength development and sealing performance with reduced greenhouse gas emissions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts industrial waste materials (fly ash, silica fume, metakaolin) that would otherwise be environmental burdens into valuable cementitious components. These pozzolan materials react with calcium hydroxide from hydraulic cement to form additional binding products, turning potential waste into beneficial sealing and strengthening agents

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The lightweight settable composition provides effective sealing of voids in well bores with reduced energy consumption and environmental footprint, achieving compressive strengths suitable for remedial cementing operations while minimizing costs.

Implementation Method 1

settable compositions that hydraulically sets or otherwise develops compressive strength

Methodology Applied
Scientific EffectHydraulic setting:

Implementation Method 2

lightweight settable composition wherein the composition is free of Portland cement and comprises pumice... having a density of less than 1618 kilograms per cubic metre

Methodology Applied
Scientific EffectBuoyancy: Archimedes' Principle (Buoyancy)

Data Source

PatentEP2991946B1Pumice-containing remedial compositions and methods of use
Publication Date: 2018.10.17 HALLIBURTON ENERGY SERVICES INC

AI summary

Methods and compositions are provided that utilize pumice and various additives. An embodiment provides a method of remedial cementing in a subterranean formation comprising: providing a lightweight settable composition comprising pumice, a calcium activator, and water, wherein the lightweight settable composition has a density of less than about 13.5 pounds per gallon and is free of Portland cement; and using the lightweight settable composition in a remedial cementing method to seal one or more voids in a well bore. Also provided are pumice-containing remedial compositions and systems for remedial cementing.