Purging Compound for Polyamide Removal from Extruders

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Solution Overview

Problem

The transition from polar to non-polar thermoplastic resins, such as from nylon to polyethylene, is challenging due to the strong affinity of nylon for metals in the extruder, leading to prolonged downtime and increased costs for film manufacturers.

Innovation Solution

A masterbatch composed of a non-polar base polymer, such as polyethylene or polypropylene, compounded with an ethylene-methacrylate copolymer, minerals like calcium carbonate, and antioxidants, which facilitates the removal of polyamides from the extruder by enhancing filler acceptance, thermal resistance, and stability, allowing for a smoother transition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of time

If conventional purging compounds are used to remove polyamides from the extruder, then the extruder can be cleaned, but the transition time remains prolonged due to the strong affinity of nylon for metals

Engineering Contradiction:
Improvetransition timeVSAvoidcleaning effectiveness
Core Design Contradiction:
Loss of timeVSReliability

Solution Approach 1:

The purging compound combines polyethylene base resin with ethylene-methacrylate copolymer and mineral fillers to create a composite material that simultaneously provides non-polar characteristics for polyamide affinity and enhanced mechanical properties for effective purging action, resolving the contradiction between cleaning effectiveness and transition time

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention changes the chemical composition parameters of the purging compound by incorporating specific copolymers with controlled polarity and mineral content, transforming the material properties to achieve both rapid polyamide removal and short purge duration

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the extruder is cleaned thoroughly to remove all polyamide residues, then product quality is maintained, but material wastage and costs increase significantly

Engineering Contradiction:
Improveproduct qualityVSAvoidmaterial wastage
Core Design Contradiction:
ReliabilityVSLoss of substance

Solution Approach 1:

The purging compound is designed as a consumable material that is deliberately discarded after performing its purging function, replacing the need for extensive polyamide residue removal and reducing overall material wastage while maintaining product quality

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The purging compound acts as an intermediary substance between polyamide and polyethylene production, facilitating the transition by absorbing polyamide residues through its polar groups and then being easily removed, thereby protecting product quality while minimizing waste

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If polyethylene is used as the base polymer for the purging compound, then the compound is readily purged out after use, but the affinity for polar polyamides is reduced

Engineering Contradiction:
Improvepurge removal easeVSAvoidpolyamide affinity
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The purging compound exhibits local quality differentiation where the polyethylene base provides non-polar regions for easy removal while the ethylene-methacrylate copolymer segments provide polar regions for polyamide affinity, allowing the single material to perform both functions

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

By combining polyethylene with polar copolymers and mineral fillers, the invention creates a composite where different components perform different functions: polyethylene ensures easy purging while copolymer segments provide polyamide binding capability

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This solution reduces transition time, minimizes material wastage, and lowers costs by effectively purging polyamides from the extruder, ensuring stable extruder pressure and film output during the transition process.

Implementation Method 1

The additive resin in this masterbatch has an increased polarity that helps in having an improved filler acceptance

Methodology Applied
Scientific EffectPolarity:

Implementation Method 2

The masterbatch due to the ethylene copolymer additive resin also has a higher thermal resistance which is an advantage in blends with Engineering resins such as Nylon

Methodology Applied
Scientific EffectThermal resistance:

Implementation Method 3

a minor amount (about 1%) of a suitable antioxidant

Methodology Applied
Scientific EffectOxidation: Oxidation

Data Source

PatentUS8492473B2Compound for purging residual polyamides from an extruder
Publication Date: 2013.07.23 INGENIA POLYMERS CORPORATION
  • US8492473B2 patent drawing
  • US8492473B2 patent drawing
  • US8492473B2 patent drawing

AI summary

A purging compound for purging an extruder of polyamides or other polar thermoplastic resins for transitioning to the extrusion of a non-polar thermoplastic resin, includes a non-polar base polymer compounded with an ethylene-methacrylate copolymer, up to 15% of a mineral, and about 1% of a suitable antioxidant.