Photovoltaic Module Encapsulant Ionizing Treatment for Recycling

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Solution Overview

Problem

Current recycling methods for photovoltaic modules are energy-intensive and environmentally costly due to the ductility of encapsulating polymer materials like EVA, making it difficult to efficiently separate and recover materials.

Innovation Solution

An ionizing treatment is applied to modify the mechanical properties of the polymer encapsulant, making it more brittle and easier to machine into smaller chips, followed by mechanical processing to facilitate recycling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If mechanical machining is applied directly to the encapsulant without prior treatment, then the encapsulant can be processed, but the ductility of the polymer material causes slow machining speed and difficult separation

Engineering Contradiction:
Improvemachining speedVSAvoidease of machining
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent applies an ionizing treatment (such as electron beam irradiation or gamma radiation) to the encapsulant before mechanical machining to modify its mechanical properties. This preliminary action transforms the ductile polymer material into a more brittle state, enabling faster and easier machining operations. The ionizing treatment creates free radicals that initiate crosslinking or chain scission, fundamentally changing the material's response to mechanical stress.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the physical and mechanical parameters of the encapsulant by applying ionizing radiation. This treatment modifies the polymer chain structure through crosslinking or degradation, transforming the material from a ductile state to a brittle state. The parameter change enables the encapsulant to be easily machined into chips or granules, facilitating subsequent separation and recycling of photovoltaic cells.

Inventive Principle:
Principle #35Parameter changes

2Loss of energy

If traditional recycling methods are used, then materials can be separated, but the process is energy-intensive and environmentally costly

Engineering Contradiction:
Improveenergy consumptionVSAvoidrecycling efficiency
Core Design Contradiction:
Loss of energyVSProductivity

Solution Approach 1:

The patent replaces traditional high-energy mechanical separation methods with an ionizing treatment approach. Instead of using forceful mechanical means to separate the encapsulant from photovoltaic cells, the method uses ionizing radiation to modify the encapsulant's properties, allowing for easier and less energy-intensive separation. This substitution significantly reduces energy consumption while improving recycling efficiency.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The ionizing treatment acts as an intermediary that facilitates the separation process. By applying radiation energy, the encapsulant's mechanical properties are modified in between the initial state (ductile, difficult to separate) and the final state (brittle, easy to machine). This intermediary treatment enables efficient separation without requiring excessive energy input or complex mechanical systems.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method reduces energy consumption and environmental impact by enabling faster and more efficient machining, increasing chip production by up to 70% in mass and 60% in volume, allowing for easier recovery and reuse of materials.

Implementation Method 1

irradiation of the functional device by an ionizing treatment modifying the mechanical properties of the encapsulant

Methodology Applied
Scientific EffectIonizing radiation: Ionisation

Data Source

PatentEP4378654A1Processing method for recycling photovoltaic module
Publication Date: 2024.06.05 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP4378654A1 patent drawingFigure 1~2
  • EP4378654A1 patent drawingFigure 3(a)~4
  • EP4378654A1 patent drawing

AI summary

Processing method for recycling a functional device, in particular a photovoltaic module (M), the functional device comprising at least one of a photovoltaic cell (20) or a light-emitting diode (LED) embedded in an encapsulant (21) comprising a polymer material, the process comprising the following steps: (a) irradiation of the functional device by an ionizing treatment modifying the mechanical properties of the encapsulant, and (b) machining of the encapsulant (21), in order to reduce it to chips.