Multi-layered PVD Coating for Plastic Substrates

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Solution Overview

Problem

Physical vapor deposition (PVD) coatings on plastic components lack durability and adhesion, especially after weathering and humidity exposure, necessitating improved multi-layered coating systems to replace traditional chrome plating.

Innovation Solution

A multi-layered coating system comprising a substrate with a PVD metallic layer, an adhesion layer containing a silicate such as kaolin group minerals and latex, and a protective coating layer, where the adhesion layer is present in high weight percentage and the metallic layer has a specific thickness range, enhancing adhesion and durability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If traditional chrome plating is used, then aesthetic appearance is achieved, but environmental toxicity and disposal complexity increase

Engineering Contradiction:
Improvedisposal complianceVSAvoidhexavalent chromium toxicity
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and eliminates hexavalent chromium from the plating process entirely, replacing it with a multi-layer PVD coating system using aluminum, zirconium, and clear coat materials that provide equivalent aesthetic and protective functions without the toxic environmental concerns

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention uses a composite multi-layer coating structure consisting of aluminum PVD layer, zirconium intermediate layer, and clear coat protective layer, which together replicate the appearance and durability of chrome plating while using environmentally benign materials

Inventive Principle:
Principle #40Composite materials

2Object-affected harmful factors

If PVD metallized layer is applied to plastic substrate, then chrome plating alternative is provided, but adhesion durability deteriorates after weathering and humidity exposure

Engineering Contradiction:
Improveenvironmental exposure resistanceVSAvoidcoating adhesion
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent applies preliminary surface treatment to the plastic substrate before PVD coating deposition, including plasma treatment or chemical etching, to create surface characteristics that enhance adhesion of the aluminum layer to the plastic substrate, preventing delamination under environmental stress

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The invention employs a composite multi-layer structure with aluminum PVD layer, zirconium intermediate layer, and clear coat protective layer, where each layer is specifically designed to address adhesion and durability challenges under weathering and humidity conditions

Inventive Principle:
Principle #40Composite materials

3Reliability

If multi-layered coating system with adhesion layer is implemented, then coating durability is improved, but manufacturing process complexity increases

Engineering Contradiction:
Improvecoating durabilityVSAvoidcoating process steps
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines multiple functional layers (adhesion promotion, metallization, protection) into an integrated multi-layer coating system that is applied in a coordinated sequence, where the combined effect provides superior durability that exceeds the sum of individual layers

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The multi-layered coating system significantly improves the adhesion and durability of PVD coatings on plastic substrates, providing a more durable and aesthetically pleasing alternative to chrome plating while avoiding the toxicity and environmental concerns associated with hexavalent chromium.

Implementation Method 1

The PVD metallized layer can be deposited onto a plastic substrate through changes in the physical state of the metal (i.e., solid to gas to solid)

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Implementation Method 2

The PVD metallized layer can be deposited by a variety of methods, for example, via thermal evaporation or sputtering

Methodology Applied
Scientific EffectThermal evaporation: Evaporation

Implementation Method 3

The PVD metallized layer can be deposited by a variety of methods, for example, via thermal evaporation or sputtering

Methodology Applied
Scientific EffectSputtering: Sputtering

Data Source

PatentUS11697872B2Multi-layered coating system for a substrate and method of making the same
Publication Date: 2023.07.11 GM GLOBAL TECHNOLOGY OPERATIONS LLC
  • US11697872B2 patent drawing
  • US11697872B2 patent drawing

AI summary

A multi-layered coating system for a substrate and a method for preparing the multi-layered coating system are provided herein. The multi-layered coating system includes a substrate, a metallic layer disposed adjacent to at least a portion of the substrate, an adhesion layer disposed adjacent to at least a portion of the metallic layer, and a protective coating layer disposed adjacent to at least a portion of the adhesion layer. The metallic layer includes a metal, an oxide of the metal, or a combination thereof. The adhesion layer includes a silicate and latex.