Pyrene Derivative Stabilizes OLED Deposition Rate Variations

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Solution Overview

Problem

Organic electroluminescent elements prepared using existing light emitting materials exhibit high variations in luminous efficiency, driving voltage, and durability, which are not consistently at the required level, especially with changes in film forming rates during vacuum deposition.

Innovation Solution

Incorporating a pyrene derivative with a specific structure, represented by general formula (I), into the organic electroluminescent element's light emitting layer, which includes a compound with specific substituents and a host material like anthracene, to stabilize performance and reduce dependency on deposition rate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If existing light emitting materials are used with conventional vacuum deposition methods, then the organic electroluminescent element can be manufactured, but the luminous efficiency, driving voltage, and durability show high variations and do not reach required performance levels

Engineering Contradiction:
Improveperformance consistencyVSAvoidluminous efficiency variation
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent introduces a novel compound structure (formula I) with specific molecular architecture including heteroatom-containing six-membered rings and aromatic hydrocarbon groups, which fundamentally changes the material parameters to achieve consistent high performance across different deposition rates

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material strategy by combining the novel compound of formula (I) with host materials and dopants in the light-emitting layer, creating a multi-component system that maintains performance stability regardless of deposition rate variations

Inventive Principle:
Principle #40Composite materials

2Productivity

If film forming rate is changed during vacuum deposition, then deposition time and productivity can be adjusted, but the luminous efficiency, driving voltage, and durability of the organic electroluminescent element show high variations

Engineering Contradiction:
Improvedeposition rateVSAvoiddriving voltage stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent changes the chemical parameters of the light-emitting material to formula (I), which has molecular structure characteristics that enable stable film formation and charge transport across a wide range of deposition rates, thereby decoupling productivity from performance reliability

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If film forming rate is changed during vacuum deposition, then manufacturing flexibility can be improved, but the luminous efficiency, driving voltage, and durability show high variations and fail to reach required levels

Engineering Contradiction:
Improvedeposition process flexibilityVSAvoidluminous efficiency control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent modifies the material parameters by introducing compound (I) with specific structural features that provide process window flexibility, allowing manufacturers to vary deposition rates without compromising luminous efficiency control or final product quality

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic electroluminescent element achieves improved luminous efficiency, driving voltage, and durability with reduced dependency on deposition rate, making it suitable for display and illumination devices.

Implementation Method 1

utilize, for light emitting, energy of the exciton generated as a result of recombination of electrons injected from a cathode and holes injected from an anode in the organic layer

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

a light emitting layer including the light emitting material is formed at a film forming rate of 5 angstroms/s to 30 angstroms/s according to a vacuum deposition method

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS9620720B2Organic electroluminescent element, and light emitting device, display device and lighting device each using organic electroluminescent element
Publication Date: 2017.04.11 UDC IRELAND
  • US9620720B2 patent drawing
  • US9620720B2 patent drawing
  • US9620720B2 patent drawing

AI summary

An organic electroluminescent element including a substrate, a pair of electrodes including an anode and a cathode, disposed on the substrate, and at least one organic layer including a light emitting layer, disposed between the electrodes, in which at least one kind of compound represented by the following general formula (I) is contained in any layer of the at least one organic layer. The organic electroluminescent element has good luminous efficiency, driving voltage, and driving durability, and has low dependence of such performance on a deposition rate:wherein X, Q, R1 to R8 are as defined in the application.