Pyrene Derivative Stabilizes OLED Performance Across Deposition Rates

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Solution Overview

Problem

Existing organic electroluminescent elements exhibit high variations in luminous efficiency, driving voltage, and driving durability when the film forming rate is changed during vacuum deposition, failing to meet recent performance requirements.

Innovation Solution

Incorporating a pyrene derivative with a specific structure, represented by general formula (I), into the organic electroluminescent element, which is contained in at least one organic layer, including a light emitting layer, to stabilize performance across varying deposition rates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional light emitting materials are used in organic electroluminescent elements, then the elements can operate at low voltage with high luminance, but the luminous efficiency, driving voltage, and driving durability show high variations when film forming rate is changed during vacuum deposition

Engineering Contradiction:
Improveperformance stabilityVSAvoidfilm forming rate control
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent introduces a specific molecular structure parameter (pyrene derivative with formula I) that changes the material's inherent properties. This structural parameter makes the light emitting layer's performance insensitive to deposition rate variations, thereby stabilizing luminous efficiency, driving voltage, and driving durability across different manufacturing conditions

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite approach by combining the pyrene derivative compound with host materials (such as mCP, TCTA, or TAPC) to create a light emitting layer. This composite material system provides both high performance and reduced sensitivity to deposition parameters, as the pyrene derivative acts as a dopant or key component within the composite structure

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If the film forming rate is changed during vacuum deposition of light emitting layer, then manufacturing flexibility is improved, but luminous efficiency, driving voltage, and driving durability show high variations

Engineering Contradiction:
Improvedeposition rate flexibilityVSAvoidperformance consistency
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

By changing the molecular structure parameter to a pyrene derivative with formula I, the material achieves a state where performance metrics remain consistent across a wide range of deposition rates. This allows manufacturers to flexibly adjust deposition rates without compromising device performance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The pyrene derivative creates an equipotential performance state where luminous efficiency, driving voltage, and driving durability remain relatively constant despite variations in deposition rate. This is achieved through the material's inherent properties that buffer against deposition parameter changes

Inventive Principle:
Principle #12Equipotentiality

3Ease of manufacture

If conventional materials are used, then existing technology can be maintained, but performance does not reach the level required by recent applications

Engineering Contradiction:
Improvetechnology continuityVSAvoidperformance level
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent combines the pyrene derivative with conventional host materials to create a composite light emitting layer that maintains compatibility with existing manufacturing processes while achieving superior performance levels required for modern display and lighting applications

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The invention introduces a specific local molecular structure (pyrene derivative with formula I) into the light emitting layer that provides enhanced performance characteristics. This local structural improvement elevates the overall device performance without requiring complete redesign of the manufacturing process

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The organic electroluminescent element achieves good luminous efficiency, driving voltage, and driving durability with reduced dependence on deposition rate, enabling the production of high-performance devices such as display and illumination devices.

Implementation Method 1

utilize, for light emitting, energy of the exciton generated as a result of recombination of electrons injected from a cathode and holes injected from an anode in the organic layer

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

formed by a vacuum deposition method

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS9627623B2Organic electroluminescent element, compound, and light emitting device, display device and lighting device each using organic electroluminescent element
Publication Date: 2017.04.18 UDC IRELAND
  • US9627623B2 patent drawing
  • US9627623B2 patent drawing
  • US9627623B2 patent drawing

AI summary

An organic electroluminescent element including a substrate, a pair of electrodes including an anode and a cathode, disposed on the substrate, and at least one organic layer including a light emitting layer, disposed between the electrodes. At least one kind of a compound represented by the following general formula (I) is contained in any layer of the at least one organic layer. The organic electroluminescent element has good luminous efficiency, driving voltage, and driving durability, and has low dependence of such performance on a deposition rate.Wherein: L1 to L4, n1 to n4, A1, A5, A6, A10 and, R are as defined in the application.