Pyridine Dopant for Organic EL Luminous Efficiency

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Solution Overview

Problem

Existing organic electroluminescence (EL) devices face challenges with high driving voltage requirements and low luminance and luminous efficiency, necessitating improvements in material performance to reduce power consumption and enhance emission efficiency.

Innovation Solution

A novel compound with a specific molecular structure, represented by formulas (1) to (5), is introduced as a dopant material for the emitting layer, optimizing energy transfer and molecular arrangement to enhance luminous efficiency in organic EL devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If conventional organic EL device materials are used, then the device structure is simple, but the luminous efficiency is low and driving voltage is high

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddriving voltage
Core Design Contradiction:
Loss of energyVSPower

Solution Approach 1:

The patent applies parameter changes by modifying the molecular structure of the dopant material, specifically introducing a pyridine ring and adjusting substituent groups (R1-R6) to optimize energy transfer properties. This structural parameter modification enables improved luminous efficiency and reduced driving voltage in the organic EL device

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining the pyridine-based dopant compound with a host material in the emitting layer. This composite approach creates synergistic effects where the dopant enhances energy transfer and the host provides structural support, resulting in improved luminous efficiency and reduced power consumption

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional dopant materials are used, then the device structure is simple, but the external quantum efficiency is low

Engineering Contradiction:
Improveexternal quantum efficiencyVSAvoidmolecular structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent modifies molecular parameters by changing the core structure to a pyridine ring and adjusting substituent groups (R1-R6) to optimize energy transfer properties. This parameter optimization directly improves external quantum efficiency while maintaining reasonable structural complexity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent applies segmentation by dividing the molecular structure into distinct functional regions: the pyridine core for energy transfer, substituent groups for structural stability, and specific positioning of these groups to optimize electronic properties. This segmented design enhances external quantum efficiency through improved energy transfer pathways

Inventive Principle:
Principle #1Segmentation

3Illumination intensity

If existing emitting layer materials are used, then the manufacturing process is simple, but the emission peak wavelength performance is insufficient

Engineering Contradiction:
Improveemission peak wavelengthVSAvoidmaterial synthesis complexity
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The patent optimizes emission peak wavelength by changing molecular parameters including the pyridine core structure and substituent groups (R1-R6). These parameter adjustments allow tuning of the emission spectrum to achieve desired wavelength performance while maintaining feasible synthesis routes

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of this compound significantly improves luminous efficiency in organic EL devices by reducing energy loss and optimizing energy transfer, leading to higher external quantum efficiency and emission peak wavelength performance.

Implementation Method 1

An organic electroluminescence (EL) device is considered to be a promising inexpensive large full-color display that utilizes solid-state emission... When an electric field is applied between the electrodes, electrons are injected from the cathode, and holes are injected from the anode. The electrons and the holes recombine in the emitting layer to produce an excited state, and the energy is emitted as light when the excited state returns to the ground state.

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS10435350B2Organic electroluminecence device
Publication Date: 2019.10.08 IDEMITSU KOSAN CO LTD
  • US10435350B2 patent drawing
  • US10435350B2 patent drawing
  • US10435350B2 patent drawing

AI summary

A compound is represented by the following formula (1). In the formula (1), Ar is a substituted or unsubstituted aryl group including 6 to 30 ring carbon atoms, Ra are independently a substituted or unsubstituted alkyl group including 1 to 15 carbon atoms, or a substituted or unsubstituted cycloalkyl group including 3 to 15 carbon atoms, Rb1 to Rb4 are independently a halogen atom, a cyano group, a substituted or unsubstituted alkyl group including 1 to 15 carbon atoms, or the like, Rc1 to Rc10 are independently a hydrogen atom, a halogen atom, a cyano group, a substituted or unsubstituted alkyl group including 1 to 15 carbon atoms, or the like, * is a bonding position at which one of Rc1 to Rc10 is bonded to either nitrogen atom, x is an integer from 0 to 3, y is an integer from 0 to 4, and z are independently an integer from 0 to 5.