Pyrolytic Carbon Holder for SiC Film Cleaning

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Solution Overview

Problem

Existing film forming apparatuses face challenges in extending the lifespan of members and improving cleaning efficiency when forming silicon carbide (SiC) films, as conventional methods either generate dust, consume excessive fluorine-containing gases, or fail to sufficiently remove reaction products, leading to poor workability and shortened lifespans.

Innovation Solution

A film forming method and apparatus that utilize a holder with a surface formed by pyrolytic carbon, which is resistant to fluorine-containing gases, allowing for efficient cleaning and extending the lifespan of members by using a fluorine-containing gas like ClF3 for removing reaction products while minimizing consumption and damage to upstream components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Duration of action of stationary object

If a conventional holder with SiC coating is used for forming SiC films, then the film formation process can proceed, but the holder lifespan is short and cleaning efficiency is poor due to dust generation and excessive fluorine gas consumption

Engineering Contradiction:
Improveholder lifespanVSAvoiddust generation during cleaning
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The holder surface material is changed from SiC coating to pyrolytic carbon coating. This parameter change in material composition provides resistance to fluorine-containing gases during cleaning, preventing dust generation and extending holder lifespan while maintaining film formation capability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The holder employs a composite structure with pyrolytic carbon coating on the surface. This composite material combines the benefits of carbon's resistance to fluorine gases with the underlying holder structure, achieving both extended lifespan and reduced harmful emissions during cleaning operations

Inventive Principle:
Principle #40Composite materials

2Productivity

If fluorine-containing gas is supplied to remove reaction products from the apparatus, then cleaning effectiveness improves, but gas consumption increases and upstream components suffer damage

Engineering Contradiction:
Improvecleaning efficiencyVSAvoidfluorine gas consumption
Core Design Contradiction:
ProductivityVSLoss of substance

Solution Approach 1:

The pyrolytic carbon coating acts as an intermediary protective layer between the fluorine-containing cleaning gas and the holder substrate. This mediator allows the cleaning gas to effectively remove reaction products while the carbon coating absorbs the harmful effects, reducing gas consumption and preventing damage to upstream components

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of operation

If the holder surface is made resistant to fluorine-containing gases, then cleaning efficiency improves and gas consumption decreases, but the holder material selection becomes more restricted

Engineering Contradiction:
Improvecleaning easeVSAvoidmaterial selection flexibility
Core Design Contradiction:
Ease of operationVSAdaptability or versatility

Solution Approach 1:

The holder is segmented into functional zones: the surface layer is specifically designed with pyrolytic carbon coating for fluorine gas resistance during cleaning, while the bulk structure can be made from appropriate materials for mechanical support and thermal management. This segmentation allows optimization of each zone for its specific function

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method effectively extends the lifespan of holders and improves cleaning efficiency by using pyrolytic carbon surfaces, reducing dust generation, and minimizing fluorine gas consumption, thereby reducing damage to upstream components and enhancing the quality of SiC film formation.

Implementation Method 1

a plate-shaped member having at least a surface formed by pyrolytic carbon into the processing container to place the plate-shaped member on the stage, and supplying a fluorine-containing gas into the processing container

Methodology Applied
Scientific EffectChemical inertness:

Implementation Method 2

removing a reaction product, which has been adhered to a part other than the substrate to be processed during the forming the silicon carbide film, by loading a plate-shaped member having at least the surface formed by pyrolytic carbon into the processing container to place the plate-shaped member on the stage, and supplying a fluorine-containing gas into the processing container

Methodology Applied
Scientific EffectChemical etching:

Implementation Method 3

forming the silicon carbide film on the substrate to be processed by loading a holder that holds the substrate to be processed into a processing container of a film forming apparatus to place the holder on a stage, and supplying a raw material gas into the processing container

Methodology Applied
Scientific EffectEpitaxial growth: Epitaxy

Data Source

PatentUS12065732B2Film forming method and film forming apparatus
Publication Date: 2024.08.20 TOKYO ELECTRON LTD
  • US12065732B2 patent drawing
  • US12065732B2 patent drawing
  • US12065732B2 patent drawing

AI summary

A film forming method of forming a silicon carbide film on a substrate to be processed includes: forming the silicon carbide film on the substrate to be processed by loading a holder that holds the substrate to be processed into a processing container of a film forming apparatus to place the holder on a stage, and supplying a raw material gas into the processing container; and removing a reaction product, which has been adhered to a part other than the substrate to be processed during the forming the silicon carbide film, by loading a plate-shaped member having at least a surface formed by pyrolytic carbon into the processing container to place the plate-shaped member on the stage, and supplying a fluorine-containing gas into the processing container.