Pyrolytic Carbon-Supported Metal Catalyst Synthesis

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing methods for producing carbon-supported catalytically active metal species are limited by the need for specific metal compounds, complex pre-treatment processes, and the difficulty in using certain metal oxides due to solubility issues, which restricts the range of catalytically active species that can be generated and increases production time and costs.

Innovation Solution

A method involving a eutectic solvent mixture with hydrogen bond donors and acceptors is used to pyrolyze metal compounds at controlled temperatures, allowing for the simultaneous formation of carbon-supported metal species, including oxides, in a single step, thereby overcoming solubility limitations and simplifying the process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If wet-chemical metallization is used to produce carbon-supported catalysts, then metal species can be applied to the carbon surface, but the process requires complex pre-treatment of activated carbon and removal of corrosive residues

Engineering Contradiction:
Improveease of catalyst productionVSAvoidcomplexity of pre-treatment process
Core Design Contradiction:
Ease of manufactureVSDevice complexity

Solution Approach 1:

The patent combines the carbon support preparation and metal species application into a single simultaneous process. The metal compound serves dual functions: as the metal source for the catalyst and as a template for carbon formation, eliminating the need for separate carbon preparation and metal impregnation steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The metal compound is introduced into the reaction system before carbon formation occurs. This preliminary placement of the metal compound ensures it is positioned correctly on the carbon support structure from the beginning, avoiding subsequent complex treatment steps for residue removal.

Inventive Principle:
Principle #10Preliminary action

2Adaptability or versatility

If traditional impregnation methods are used, then metal compounds can be applied to carbon support, but the range of usable metals is limited and production time increases

Engineering Contradiction:
Improverange of metal speciesVSAvoidproduction time
Core Design Contradiction:
Adaptability or versatilityVSLoss of time

Solution Approach 1:

The patent changes the fundamental parameters of the synthesis process by using thermal decomposition instead of wet-chemical impregnation. This allows the use of metal compounds that are not soluble in traditional impregnation media, significantly expanding the range of applicable metal species including those that form stable oxides.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent extracts the limitation of solubility requirements by completely removing the liquid impregnation medium from the process. By using thermal decomposition in the gas phase or from solid precursors, the method eliminates the need for metal compounds to be soluble in any solvent, thus expanding metal selection.

Inventive Principle:
Principle #2Taking out (Extraction)

3Reliability

If activated carbon is used as support material, then it provides large surface area and chemical inertness, but requires time-consuming pre-treatment to remove impurities

Engineering Contradiction:
Improvecatalyst performanceVSAvoidpre-treatment time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The metal compound is positioned on the carbon support structure before the carbon matrix is fully formed or immediately during its formation. This preliminary action ensures proper metal distribution without requiring subsequent pre-treatment steps to remove impurities or reposition metal species.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent merges the carbon support formation and metal species deposition into a single integrated process. The carbon matrix and metal catalyst are formed simultaneously in one reaction step, eliminating the need for separate pre-treatment and impurity removal operations.

Inventive Principle:
Principle #5Merging (Combining)

4Reliability

If carbon-supported metal particles are produced by traditional methods, then catalytic activity can be achieved, but production costs increase due to complex processes

Engineering Contradiction:
Improvecatalytic activityVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent combines multiple process steps (carbon preparation, metal impregnation, drying, and calcination) into a single thermal decomposition reaction. This consolidation maintains catalytic activity while significantly reducing production costs by eliminating intermediate steps and reducing processing time.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses simple, inexpensive metal compounds as precursors that decompose thermally to form the active metal catalyst. These precursor materials are cheaper and easier to handle than traditional metal salts used in wet-chemical methods, reducing overall production costs while maintaining catalyst performance.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the production of catalytically active carbon-supported metal species with enhanced activity and broader metal oxide utilization, reducing production time and costs while maintaining or exceeding the catalytic performance of traditional methods.

Implementation Method 1

c) pyrolyzing the pyrolysis mixture produced in step b) at a temperature of 250° C. to 1000° C.

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Implementation Method 2

wherein the at least one eutectic solvent mixture (x) at least one hydrogen bond donor and (y) at least one contains hydrogen bond acceptor

Methodology Applied
Scientific EffectHydrogen bonding:

Implementation Method 3

c) pyrolyzing the pyrolysis mixture produced in step b) at a temperature of 250° C. to 1000° C., so that at least one metal species-having particles are obtained

Methodology Applied
Scientific EffectThermal decomposition: Decomposition (biological)

Data Source

PatentEP3294452A1Pyrolytic method for the production of particles containing at least one metal species
Publication Date: 2018.03.21 FRAUNHOFER GESELLSCHAFT ZUR FORDERUNG DER ANGEWANDTEN FORSCHUNG EV

AI summary

The invention relates to a method for producing particles containing at least one metal species with the aid of an eutectic solvent mixture, to carbon particles that are produced accordingly and contain at least one metal species, to a method for hydrogenating at least one hydrogenation compound, to a method for cross-coupling aryl halides or vinyl halides and terminal alkynes, and to a method for producing metal particles, metal complex particles, metal oxide particles and/or metal mixed oxide particles.