Pyrolytic Reactor Annular Nozzle Shockwave Mixing

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Solution Overview

Problem

Traditional pyrolytic reactors face challenges in achieving high conversion and selectivity for desired products like acetylene due to non-uniform mixing of feedstock and carrier streams, leading to undesirable reactions and reduced efficiency.

Innovation Solution

A pyrolytic reactor design that injects feedstock using multiple annularly arranged nozzles, creating a shockwave in the reaction zone to mix the carrier gas stream and feedstock simultaneously, eliminating the need for a separate mixing zone and optimizing conditions for high temperature and rapid quenching to favor acetylene formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Device complexity

If a single row of uniform injectors is used to inject feedstock, then the device complexity is reduced, but the mixing uniformity of feedstock and carrier stream deteriorates

Engineering Contradiction:
Improveinjector configurationVSAvoidmixing uniformity
Core Design Contradiction:
Device complexityVSStability of the object's composition

Solution Approach 1:

The single row of uniform injectors is segmented into multiple rows with different configurations. The patent employs a first row of injectors positioned at a first location and a second row of injectors positioned at a second location, allowing each row to contribute differently to the mixing process and achieve more uniform distribution without excessive complexity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the reactor receive different injector configurations tailored to local mixing needs. The first row of injectors is positioned to address mixing requirements at the first location, while the second row addresses requirements at the second location, creating locally optimized mixing throughout the reactor volume

Inventive Principle:
Principle #3Local quality

2Stability of the object's composition

If a mixing zone is added to ensure full mixing of carrier stream and feedstock, then the mixing uniformity improves, but the residence time increases leading to undesirable reactions

Engineering Contradiction:
Improvemixing uniformityVSAvoidresidence time
Core Design Contradiction:
Stability of the object's compositionVSLoss of time

Solution Approach 1:

Mixing is performed preliminarily through the multi-row injector configuration before the feedstock enters the reaction zone. The injectors are designed to create thorough mixing in the injection zones themselves, so that when material enters the reaction zone, it is already well-mixed and ready for immediate reaction, eliminating the need for a separate mixing zone

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The mixing function is extracted from a separate mixing zone and integrated directly into the injection system. By incorporating mixing capabilities into the injector rows positioned at different locations, the patent eliminates the need for a dedicated mixing zone that would otherwise increase residence time

Inventive Principle:
Principle #2Taking out (Extraction)

3Productivity

If high temperature combustion is used to generate carrier stream, then the pyrolysis reaction efficiency improves, but the formation of unwanted byproducts increases

Engineering Contradiction:
Improvepyrolysis reaction efficiencyVSAvoidbyproduct formation
Core Design Contradiction:
ProductivityVSObject-generated harmful factors

Solution Approach 1:

The patent carefully controls temperature parameters throughout different zones. High temperature combustion is used to generate the carrier stream for efficiency, but the multi-row injector system enables rapid cooling and temperature stabilization in subsequent zones, preventing excessive temperatures that would promote unwanted byproduct formation while maintaining reaction efficiency

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances conversion and selectivity for acetylene by ensuring uniform mixing and controlled residence times, preventing decomposition and forming higher hydrocarbons, thereby increasing the yield of acetylene and reducing the formation of less valuable products.

Implementation Method 1

The carrier gas stream is transitioned from supersonic speed to subsonic speed to create a shockwave in a reaction zone

Methodology Applied
Scientific EffectShockwave: Shock Wave

Implementation Method 2

combusting the fuel and the oxidizer in a combustion zone to create a carrier gas stream

Methodology Applied
Scientific EffectCombustion: Combustion

Implementation Method 3

exposing the feedstock to high temperature combustion gases causing the feedstock to pyrolyze into the desired unsaturated product

Methodology Applied
Scientific EffectPyrolysis: Pyrolysis

Data Source

PatentUS10279329B2Pyrolytic reactor and method of using
Publication Date: 2019.05.07 UOP LLC
  • US10279329B2 patent drawing
  • US10279329B2 patent drawing

AI summary

Methods and apparatus to produce alkynes are described. The method includes combusting fuel and an oxidizer in a combustion zone to create a carrier gas stream, which is accelerated to supersonic speed in an expansion zone. A feedstock material is injected into a feedstock injection zone using two or more pluralities of injection nozzles. The injection nozzles are arranged annularly. The carrier gas stream is transitioned from supersonic speed to subsonic speed to create a shockwave in a reaction zone. The reaction zone is directly connected to the feedstock injection zone, and the shockwave is created adjacent to the feedstock injection zone. The carrier gas stream and the feedstock material are simultaneously mixed and reacted.