Q-Carbon Hardfacing Coatings for Wear-Resistant Downhole Tools

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Solution Overview

Problem

Downhole tools in oil and gas drilling face challenges with wear and balling, where existing materials fail to provide adequate resistance to abrasive wear and clogging, leading to tool degradation and reduced efficiency.

Innovation Solution

A hardfacing coating comprising a tungsten carbide substrate with a diamond layer and a Q-carbon layer, formed using a homogenous mixture of Q-carbon and additional components, applied via laser beam or oxy-acetylene thermal spraying, providing enhanced wear resistance and anti-balling properties.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional hardfacing materials are used to protect downhole tools from abrasive wear, then wear resistance is improved, but the tools are prone to balling (clogging)

Engineering Contradiction:
Improvewear resistanceVSAvoidballing
Core Design Contradiction:
StrengthVSObject-generated harmful factors

Solution Approach 1:

The patent applies composite materials by combining Q-carbon (a superhard carbon allotrope) with diamond particles and metal matrix materials to create a hardfacing coating that simultaneously provides superior wear resistance and anti-balling properties. The composite structure integrates multiple functional components: Q-carbon for extreme hardness, diamond for wear resistance, and the metal matrix for toughness and anti-adhesion characteristics that prevent balling.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent utilizes parameter changes by transforming carbon from its conventional forms into Q-carbon through rapid quenching from the liquid state. This phase transformation creates a material with fundamentally different properties - extremely high hardness and unique surface characteristics that prevent balling. The process involves changing temperature parameters (rapid cooling from molten state) to achieve the desired material properties.

Inventive Principle:
Principle #35Parameter changes

2Object-generated harmful factors

If anti-balling coatings are applied to prevent clogging, then balling is reduced, but wear resistance is compromised

Engineering Contradiction:
Improveballing preventionVSAvoidwear resistance
Core Design Contradiction:
Object-generated harmful factorsVSStrength

Solution Approach 1:

The patent resolves this contradiction by creating a composite hardfacing material where Q-carbon and diamond provide the wear resistance function while the overall composite structure and surface properties provide the anti-balling function. Rather than applying a separate anti-balling coating that would compromise hardness, the anti-balling properties are integrated into the hardfacing material itself through the composite formulation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The hardfacing coating achieves multi-functionality by simultaneously providing wear resistance, toughness, and anti-balling properties within a single integrated material system. The Q-carbon/diamond/metal matrix composite performs multiple functions: protecting against abrasive wear, resisting impact, and preventing material adhesion that causes balling, eliminating the need for separate functional layers.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Duration of action of stationary object

If existing hardfacing materials are used, then some wear protection is achieved, but tool life is limited due to combined wear and balling

Engineering Contradiction:
Improvetool lifeVSAvoidperformance consistency
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent extends tool life by using composite materials that address both wear and balling simultaneously. The Q-carbon/diamond/metal matrix composite provides superior durability by maintaining structural integrity under combined wear and adhesion conditions, allowing the tool to operate longer without degradation from either mechanism.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The hardfacing coating provides beforehand cushioning by creating a protective barrier that prevents both wear damage and balling before they can occur during operation. The coating is applied in advance to the downhole tool surface, establishing a protective layer that resists both abrasive wear and material adhesion, thereby preventing tool failure modes before they initiate.

Inventive Principle:
Principle #11Beforehand cushioning (Prior cushioning)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hardfacing coating significantly extends the life of downhole tools by offering superior wear resistance and preventing clogging, thereby improving drilling efficiency and reducing maintenance costs.

Implementation Method 1

disposing the homogenous mixture in a laser beam path of a laser beam apparatus, wherein the homogenous mixture comprises a powder, and wherein the powder melts when disposed in the laser beam path to form a hardfacing coating on the substrate

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 2

disposing the homogenous mixture in an oxy-acetylene thermal spraying apparatus and heating the homogeneous mixture using an oxy-acetylene torch of the oxy-acetylene thermal spraying apparatus

Methodology Applied
Scientific EffectCombustion heating: Combustion

Implementation Method 3

disposing a powder comprising Q-carbon diamond into at least one cavity of a mold; applying pressure to the mold; and forming, in response to pressure, a hardfacing component via the at least one cavity

Methodology Applied
Scientific EffectCompression molding: Compression

Data Source

PatentUS10906104B2Systems and methods of fabrication and use of wear-resistant materials
Publication Date: 2021.02.02 NAT OILWELL DHT LP
  • US10906104B2 patent drawing
  • US10906104B2 patent drawing
  • US10906104B2 patent drawing

AI summary

Discussed herein are systems and methods of forming hardfacing coatings and films containing Q-carbon diamond particles for use in downhole drilling tooling and other tools where wear-resistant coating is desirable. The Q-carbon diamond-containing layers may be coated with matrix material and/or disposed in a matrix to form the coating, or the Q-carbon diamond layer may be formed directly from a diamond-like-carbon on a substrate.