QCL Analyzer Waveform Difference Minimization

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Solution Overview

Problem

Current methods for measuring gas components and their concentrations using quantum cascade lasers (QCLs) face challenges such as prolonged measurement times, reliability issues due to mechanical components, and wavelength shifts caused by injection current changes, which affect the accuracy of absorption spectrum measurements.

Innovation Solution

An analyzer and analysis method that utilize a QCL driven by a cyclic waveform, an optical receiver, and a data calculation portion with delaying, adding, time inversion, and subtracting units to produce information representing absorption characteristics by minimizing the absolute value of waveform differences, effectively eliminating wavelength shifts caused by injection current changes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If the wavelength of mid-infrared light is changed by changing temperature or injection current, then wavelength tuning is achieved, but wavelength shift and measurement accuracy deteriorate

Engineering Contradiction:
Improvewavelength tuning capabilityVSAvoidabsorption spectrum measurement accuracy
Core Design Contradiction:
Adaptability or versatilityVSMeasurement precision

Solution Approach 1:

The patent applies feedback by detecting the actual wavelength of the QCL light and comparing it with the target wavelength, then adjusting the injection current to correct any deviation. This closed-loop control ensures the wavelength remains accurately positioned despite drift or external disturbances, resolving the contradiction between wavelength tuning capability and measurement accuracy.

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent dynamically adjusts the injection current parameter to achieve precise wavelength control. By changing the injection current in a controlled manner and monitoring the resulting wavelength shifts, the system can tune the QCL to the desired wavelength while compensating for non-linear effects and maintaining measurement accuracy.

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If measurement time is prolonged to improve accuracy, then absorption spectrum measurement quality improves, but 1/f noise and drift influence increase

Engineering Contradiction:
Improveabsorption spectrum measurement accuracyVSAvoid1/f noise and drift influence
Core Design Contradiction:
Measurement precisionVSObject-affected harmful factors

Solution Approach 1:

The patent employs periodic modulation of the injection current to scan through the absorption spectrum. By using periodic square wave or triangular wave modulation, the system can rapidly cycle through wavelength ranges and perform multiple measurements quickly, reducing the impact of drift and 1/f noise while maintaining measurement accuracy through signal averaging.

Inventive Principle:
Principle #19Periodic action

Solution Approach 2:

The patent maintains continuous wavelength scanning and measurement without interruption, allowing the system to rapidly acquire spectral data. This continuous operation minimizes the time window for drift to affect measurements and enables real-time signal processing to compensate for noise, achieving high accuracy without prolonged measurement times.

Inventive Principle:
Principle #20Continuity of useful action

3Productivity

If injection current is changed at short time cycle to reduce measurement time, then measurement speed improves, but wavelength shift from frequency chirping and temperature change increases

Engineering Contradiction:
Improvemeasurement speedVSAvoidwavelength accuracy
Core Design Contradiction:
ProductivityVSMeasurement precision

Solution Approach 1:

The patent performs preliminary calibration by measuring the relationship between injection current and wavelength shift before actual measurements. This pre-characterization of frequency chirping and temperature effects allows the system to predict and compensate for wavelength shifts during rapid scanning, enabling high-speed measurements without sacrificing accuracy.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent uses real-time wavelength detection and feedback control to monitor and correct wavelength shifts caused by rapid injection current changes. By continuously measuring the actual wavelength and adjusting the current to compensate for chirping and thermal effects, the system achieves both high measurement speed and high wavelength accuracy.

Inventive Principle:
Principle #23Feedback

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for accurate measurement of absorption characteristics with reduced measurement time and improved reliability, enabling precise identification of gas components and their concentrations by stabilizing the wavelength and minimizing the influence of wavelength shifts.

Implementation Method 1

a QCL (quantum cascade laser) that receives a driving signal including a cyclic waveform and converts the driving signal to laser light in a mid-infrared range

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 2

an optical receiver that receives the laser light having passed through a sample and outputs a detected signal depending on the intensity of the laser light

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Implementation Method 3

measuring a spectrum of the light having passed through the gas

Methodology Applied
Scientific EffectAbsorption spectroscopy: Absorption Spectroscopy

Implementation Method 4

absorption characteristics of the sample

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS10345225B2Analyzer, absorption characteristic calculation circuit, and analysis method
Publication Date: 2019.07.09 SUMITOMO ELECTRIC INDUSTRIES LTD
  • US10345225B2 patent drawing
  • US10345225B2 patent drawing
  • US10345225B2 patent drawing

AI summary

An analyzer includes a quantum cascade laser that converts a cyclic driving signal to laser light; an optical receiver that receives the laser light having passed through a sample and outputs a detected signal depending on intensity of the laser light; and a data calculation portion that outputs information representing absorption characteristics of the sample. The data calculation portion includes a delaying unit that produces a time-delayed waveform by applying a time delay to a reference driving signal; an adding unit that produces a symmetrical waveform by adding the time-delayed waveform and the detected signal; a time inversion unit that produces a time-inverted waveform by time-inverting the symmetrical waveform; and a subtracting unit that produces a waveform difference between the time-inverted waveform and the symmetrical waveform. The data calculation portion repeatedly calculates the waveform difference by changing the time delay until the waveform difference is minimized.