QCM Sensor Electrode Contour Pattern for Corrosive Gas Sensitivity

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Solution Overview

Problem

QCM sensors face challenges in enhancing sensitivity for detecting corrosive gases without surface roughening or increasing fundamental oscillation frequency, which can destabilize the sensor and limit its effectiveness in monitoring low concentrations of corrosive gases.

Innovation Solution

The QCM sensor incorporates a pattern with a long contour line on the electrode, such as slits or openings, to increase the ratio of contour length to area, enhancing sensitivity by concentrating corrosion in the edge portion, thereby amplifying the change in oscillation frequency without altering the surface roughness or oscillation frequency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If surface roughening is applied to enhance sensitivity, then sensitivity to corrosive gases is improved, but sensor stability is worsened

Engineering Contradiction:
ImprovesensitivityVSAvoidstability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The invention applies local quality by creating patterns with different properties in different regions of the electrode. Specifically, edge portions are designed with higher curvature or protruding structures that concentrate corrosion, while central portions maintain smoother surfaces. This allows the sensor to achieve high sensitivity through localized corrosion concentration without compromising overall stability.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The electrode surface is segmented into distinct regions with different geometric characteristics. The pattern divides the surface into edge portions (with higher curvature or protrusions) and central portions (with lower curvature), allowing each region to serve different functions: edge portions for sensitivity enhancement through corrosion concentration, and central portions for maintaining structural stability.

Inventive Principle:
Principle #1Segmentation

2Measurement precision

If fundamental oscillation frequency is increased to improve sensitivity, then sensitivity to corrosive gases is improved, but sensor stability is worsened

Engineering Contradiction:
ImprovesensitivityVSAvoidstability
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

Instead of changing the fundamental oscillation frequency parameter, the invention changes the geometric parameters of the electrode pattern. By modifying the contour line length, curvature, and area ratios through patterning, the sensor achieves sensitivity enhancement while maintaining the original stable oscillation frequency of the quartz crystal.

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If electrode mass is increased to improve sensitivity, then sensitivity to corrosive gases is improved, but the natural oscillation frequency decreases

Engineering Contradiction:
ImprovesensitivityVSAvoidnatural oscillation frequency
Core Design Contradiction:
Measurement precisionVSSpeed

Solution Approach 1:

The invention creates a patterned electrode structure that effectively increases the surface area and contour length without proportionally increasing the mass. The patterned structure with its extended contour lines and edge portions provides more surface for corrosion interaction, enhancing sensitivity, while the overall mass remains controlled to maintain appropriate oscillation frequency.

Inventive Principle:
Principle #31Porous materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly increases the sensor's sensitivity to corrosive gases, allowing for more accurate monitoring of low concentrations without compromising stability or longevity, as demonstrated by the increased ratio of contour length to area, leading to improved detection capabilities.

Implementation Method 1

a quartz plate provided with electrodes on both principal surfaces, and is configured to oscillate the quartz plate at a natural oscillation frequency by applying a predetermined voltage to the electrodes

Methodology Applied
Scientific EffectPiezoelectric effect: Piezoelectric Effect

Implementation Method 2

the above-described natural oscillation frequency decreases along with an increase in mass of the electrodes of the QCM sensor due to corrosion by the corrosive gases

Methodology Applied
Scientific EffectCorrosion: Crevice Corrosion

Data Source

PatentUS10006885B2QCM sensor and method of manufacturing the same
Publication Date: 2018.06.26 FUJITSU LTD
  • US10006885B2 patent drawing
  • US10006885B2 patent drawing
  • US10006885B2 patent drawing

AI summary

In a QCM sensor and a method of manufacturing the same, the QCM sensor includes: a quartz plate; and an electrode provided on one and the other principal surfaces of the quartz plate, in which the electrode is provided with a pattern having a contour line in a planar view of the electrode.