QCM Sensor Buffer Electrode Design for Deposition Uniformity

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Solution Overview

Problem

Existing deposition methods for display apparatuses, such as OLEDs and LCDs, face challenges in achieving a uniform thickness of deposition films, as they lack effective real-time monitoring and control of deposition material amounts.

Innovation Solution

A quartz crystal microbalance (QCM) sensor is developed, comprising a crystal plate with buffer and electrode layers, where the electrode includes metals with a hexagonal close-packed lattice structure, and a buffer layer with higher electrical activity, allowing for real-time measurement of deposition material thickness and uniformity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional deposition methods are used without real-time monitoring, then the deposition process is simpler and faster, but the uniformity of deposition film thickness deteriorates

Engineering Contradiction:
Improveuniformity of deposition film thicknessVSAvoidcomplexity of deposition monitoring system
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The QCM sensor provides real-time feedback on deposition thickness by measuring frequency changes in the crystal plate. The sensor is positioned to receive deposition material simultaneously with the substrate, allowing continuous monitoring and control of film thickness uniformity during the deposition process

Inventive Principle:
Principle #23Feedback

Solution Approach 2:

The patent replaces complex optical or profilometric measurement systems with a mechanical vibration-based QCM sensor. The crystal plate's resonance frequency changes in response to deposited mass, providing a simple yet precise mechanical method for real-time thickness monitoring

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Strength

If the electrode layer is made thicker to improve adhesion, then adhesion performance improves, but the total resistance of the sensor increases

Engineering Contradiction:
Improveadhesion of electrode to crystal plateVSAvoidelectrical resistance of sensor
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent optimizes the thickness parameter of the electrode layer to achieve the minimum required thickness for adequate adhesion while maintaining low electrical resistance. The buffer layer composition and thickness are also adjusted to provide adhesion enhancement without adding significant resistance

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite structure consisting of a buffer layer and an electrode layer. The buffer layer (e.g., chromium, molybdenum) provides strong adhesion to the crystal plate, while the electrode layer (e.g., aluminum, gold) provides low electrical resistance, creating a synergistic multi-layer system

Inventive Principle:
Principle #40Composite materials

3Strength

If multiple buffer layers are added to improve adhesion and protection, then adhesion and durability improve, but the device structure becomes more complex

Engineering Contradiction:
Improveadhesion and protection of crystal plateVSAvoidnumber of buffer layers
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies buffer layers selectively at specific locations where adhesion and protection are most critical, such as at the interfaces between the crystal plate and electrode, or at edges prone to mechanical stress, rather than uniformly across the entire surface

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The QCM sensor enables real-time monitoring and control of deposition material thickness, ensuring a uniform deposition film, improving adhesion and sensing performance by adjusting the thickness ratio of the buffer and electrode layers, and reducing total resistance.

Implementation Method 1

a crystal plate, a buffer layer, and an electrode. The crystal plate has a first surface and a second surface

Methodology Applied
Scientific EffectResonance: Resonance

Implementation Method 2

An electrical activity of the buffer layer may be higher than an electrical activity of the electrode. A total resistance of the QCM sensor may be about 15Ω or less.

Methodology Applied
Scientific EffectElectrical Conduction: Conduction (electrical)

Data Source

PatentUS10663431B2Quartz crystal microbalance sensor for deposition monitoring
Publication Date: 2020.05.26 SAMSUNG DISPLAY CO LTD
  • US10663431B2 patent drawing
  • US10663431B2 patent drawing
  • US10663431B2 patent drawing

AI summary

A quartz crystal microbalance (QCM) sensor includes a crystal plate, a buffer layer, and an electrode. The crystal plate has a first surface and a second surface. The second surface is opposite the first surface. The buffer layer includes a first buffer layer and a second buffer layer. The first buffer layer is disposed on the first surface of the crystal plate, the second buffer layer is disposed on the second surface of the crystal plate. The electrode includes a first electrode and a second electrode. The first electrode is disposed on the first buffer layer. The second electrode is disposed on the second buffer layer. The electrode includes at least one of titanium, scandium, beryllium, cobalt, yttrium, zirconium, technetium, ruthenium, lanthanum, cerium, praseodymium, neodymium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, lutetium, hafnium, rhenium, osmium, americium, curium, berkelium, and californium.