Quantum Dot LED Barrier Structure for Moisture Isolation

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Solution Overview

Problem

Quantum dots experience reduced luminous efficiency due to temperature quenching and rapid fluorescence decline when exposed to water and oxygen, necessitating isolation from these environments for effective performance.

Innovation Solution

A quantum dot light emitting diode structure comprising a pair of electrodes, a flip chip light emitting diode, a quantum dot interlayer with symmetric barrier layers, and an inorganic package layer prepared by atomic layer deposition or organic coating, along with a micro-nano-structured organic layer, to create a water and oxygen barrier environment.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If quantum dots are exposed to water and oxygen environment, then manufacturing and operation become simpler, but fluorescence efficiency rapidly and irreversibly declines

Engineering Contradiction:
Improveease of manufactureVSAvoidfluorescence efficiency
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies thin film encapsulation using alternating organic and inorganic barrier layers deposited on the quantum dot layer. The inorganic layers (such as aluminum oxide, zirconium oxide, or silicon oxide) provide impermeable barriers to water and oxygen, while the organic layers provide adhesion and stress relief. This multi-layer thin film structure effectively prevents water and oxygen penetration, solving the contradiction between ease of manufacture and maintaining fluorescence efficiency.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent employs composite barrier structures combining different materials with complementary properties. The alternating organic and inorganic layers create a composite system where each material contributes its strengths: inorganic layers provide low permeability to water and oxygen, while organic layers provide flexibility and adhesion. This composite approach enables effective protection of quantum dots while maintaining manufacturability.

Inventive Principle:
Principle #40Composite materials

2Temperature

If quantum dots are exposed to high temperature, then heat dissipation becomes easier, but luminous efficiency decreases due to severe temperature quenching

Engineering Contradiction:
ImprovetemperatureVSAvoidluminous efficiency
Core Design Contradiction:
TemperatureVSLoss of energy

Solution Approach 1:

The thin film encapsulation structure with alternating organic and inorganic layers provides thermal management by conducting heat away from the quantum dot layer while maintaining its structural integrity. The inorganic layers have good thermal conductivity that helps dissipate heat, preventing temperature quenching and maintaining luminous efficiency at elevated temperatures.

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If barrier layers are added to isolate quantum dots from water and oxygen, then fluorescence efficiency is maintained, but device structure becomes more complex

Engineering Contradiction:
Improvefluorescence efficiencyVSAvoiddevice complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent segments the barrier protection into multiple thin alternating layers of organic and inorganic materials rather than using a single thick barrier. This segmentation allows each layer to be thin and specialized in function, achieving effective protection while keeping individual layer complexity low and enabling standard deposition processes.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The use of thin film technology allows the complex multi-layer barrier structure to be deposited in a compact and integrated manner using conventional semiconductor fabrication processes. The thin films can be deposited sequentially in a single manufacturing run, minimizing process complexity despite the multi-layer structure.

Inventive Principle:
Principle #30Flexible shells and thin films

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution effectively isolates quantum dots from water and oxygen, enhancing luminous efficiency and service life while improving light output efficiency through a robust and uniform barrier system.

Implementation Method 1

an inorganic package layer prepared by atomic layer deposition

Methodology Applied
Scientific EffectAtomic layer deposition: Deposition (physical)

Implementation Method 2

The quantum dot interlayer comprises: a quantum dot layer, and a lower barrier layer and an upper barrier layer

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 3

A micro-nano-structured organic layer is further provided on the package layer and the whitening adhesive layer

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentUS10505082B2Quantum dot light emitting diode and manufacturing method
Publication Date: 2019.12.10 HUIZHOU CHINA STAR OPTOELECTRONICS TECHNOLOGY CO LTD
  • US10505082B2 patent drawing
  • US10505082B2 patent drawing

AI summary

Provided are a quantum dot light emitting diode and a manufacturing method. The quantum dot light emitting diode comprises: a pair of electrodes, arranged side by side and spaced; a flip chip light emitting diode, disposed on the electrodes and electrically connected to the electrodes; a quantum dot interlayer, disposed on the flip chip light emitting diode; a package layer, covering the electrodes, the flip chip light emitting diode and the quantum dot interlayer; and a whitening adhesive layer, surrounding the package layer. The quantum dot interlayer is disposed to isolate the invasion of the external water and oxygen to the quantum dot layer and the light emitting diode chip to form an environment, in which the quantum dots are isolated from water and oxygen.