QLED Quantum Dot Layer Infiltration for Structural Alignment

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Solution Overview

Problem

Current QLED devices have low efficiency due to defects in the quantum dot light emitting layer, leading to uneven surfaces and internal gaps that trap carriers and prevent light emission, with existing methods focusing primarily on surface regularity rather than internal structure alignment.

Innovation Solution

A method involving the infiltration of a mixed solvent containing bifunctional molecules into the quantum dot layer to form bridges between loose quantum dots, improving the compactness and regularity of both the surface and internal structure, using a combination of temperature control, rotation, and annealing to enhance solubility and diffusion without damaging the layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional methods are used to form the quantum dot layer, then the surface regularity is improved, but the internal structure alignment remains poor leading to low device efficiency

Engineering Contradiction:
Improvesurface regularityVSAvoiddevice efficiency
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent introduces a mixed solvent containing bifunctional molecules as an intermediary substance that penetrates into the quantum dot layer. The bifunctional molecules act as mediators that simultaneously interact with multiple quantum dots, forming molecular bridges that align internal structures while maintaining surface regularity, thereby resolving the contradiction between surface quality and internal structure alignment

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent changes the chemical and physical parameters of the quantum dot layer by introducing bifunctional molecules through mixed solvent infiltration. This alters the molecular arrangement and bonding characteristics within the layer, transforming the internal structure from disordered to aligned state, which improves carrier transport and device efficiency without compromising surface regularity

Inventive Principle:
Principle #35Parameter changes

2Ease of manufacture

If the quantum dot layer is formed without bifunctional molecules, then the manufacturing process is simpler, but internal gaps trap carriers preventing light emission

Engineering Contradiction:
Improveprocess simplicityVSAvoidcarrier transport
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The bifunctional molecules in the mixed solvent serve as intermediary agents that fill internal gaps and connect quantum dots through molecular bridging. This intermediary substance enables effective carrier transport pathways without significantly complicating the manufacturing process, as the infiltration can be performed in existing fabrication sequences

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite structure within the quantum dot layer by combining quantum dots with bifunctional molecules. This composite arrangement eliminates internal gaps and creates continuous pathways for carrier transport, improving reliability while maintaining manufacturing feasibility through solvent-based infiltration

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If the quantum dot layer has loose structure, then the material deposition is easier, but the surface is uneven and internal gaps trap carriers

Engineering Contradiction:
Improvematerial depositionVSAvoidstructural uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The patent applies parameter changes by introducing bifunctional molecules that alter the structural parameters of the quantum dot layer. These molecules induce reorganization of quantum dots from loose to compact arrangement, improving surface uniformity and eliminating internal gaps while maintaining ease of deposition through solvent-based processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The mixed solvent with bifunctional molecules acts as an intermediary that facilitates structural reorganization during or after deposition. The bifunctional molecules mediate the transition from loose to compact structure by forming bridges between quantum dots, achieving structural uniformity without requiring complex deposition techniques

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the quantum efficiency and spectral characteristics of QLED devices by ensuring a more compact and regular quantum dot arrangement, allowing for improved carrier transport and light emission.

Implementation Method 1

infiltrating a mixed solvent containing a bifunctional molecule into the quantum dot layer

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

infiltrating a mixed solvent containing a bifunctional molecule into the quantum dot layer

Methodology Applied
Scientific EffectSolvation: Solvation

Implementation Method 3

raising temperature to a predetermined value

Methodology Applied
Scientific EffectHeating: Heating

Implementation Method 4

raising temperature to a predetermined value

Methodology Applied
Scientific EffectThermal expansion: Thermal Expansion

Implementation Method 5

Quantum dots have a quantum confinement effect and emit fluorescence when excited

Methodology Applied
Scientific EffectQuantum confinement effect:

Implementation Method 6

emit fluorescence when excited

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 7

performing an annealing process on the quantum dot layer

Methodology Applied
Scientific EffectAnnealing: Annealing

Implementation Method 8

performing an annealing process on the quantum dot layer

Methodology Applied
Scientific EffectHeat treatment: Heat Treatment

Data Source

PatentUS10347836B2QLED device and manufacturing method thereof, QLED display panel and QLED display device
Publication Date: 2019.07.09 BOE TECHNOLOGY GROUP CO LTD
  • US10347836B2 patent drawing
  • US10347836B2 patent drawing
  • US10347836B2 patent drawing

AI summary

A QLED device and manufacturing method thereof, a QLED display panel and a QLED display device are disclosed which improve the surface and internal structure of the quantum dot layer in the QLED devices. The method for manufacturing a QLED device includes forming a first electrode layer; forming a quantum dot layer on the first electrode layer; infiltrating a mixed solvent containing a bifunctional molecule into the quantum dot layer so as to improve the structure of the quantum dot layer; and forming a second electrode layer on the quantum dot layer.