Quantum Dot Coating Without Phosphonic Acid

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Solution Overview

Problem

Existing methods for producing quantum dots lack effective methods for coating or layering that exclude phosphonic acid or metal phosphonate species, which can hinder the performance and emission efficiency of quantum dots.

Innovation Solution

A method for forming core-shell quantum dots by subjecting core quantum dots, which are free or substantially free of phosphonic acid or metal phosphonate species, to a high temperature process using reactants that do not include these species, thereby forming a coating or layer without phosphonic acid or metal phosphonate presence.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If phosphonic acid or metal phosphonate species are present during quantum dot coating, then the coating process can proceed, but the emission efficiency and optical properties of the quantum dots deteriorate

Engineering Contradiction:
Improveemission efficiencyVSAvoidphosphonic acid or metal phosphonate species presence
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent removes phosphonic acid or metal phosphonate species from the quantum dot surface before coating by treating the core quantum dots with a solution that extracts these harmful species. This extraction process eliminates the harmful factors that would otherwise deteriorate emission efficiency, allowing the subsequent coating process to proceed with improved optical properties.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs a preliminary treatment step before the coating process to remove phosphonic acid or metal phosphonate species from the quantum dot surface. This preliminary action ensures that the harmful species are eliminated before they can interfere with the coating process or deteriorate the emission efficiency of the final core-shell quantum dots.

Inventive Principle:
Principle #10Preliminary action

2Stability of the object's composition

If a coating process is applied to quantum dots, then the quantum dots gain protective layers and improved stability, but the presence of phosphonic acid or metal phosphonate species hinders the coating quality and emission properties

Engineering Contradiction:
Improvequantum dot stabilityVSAvoidcoating quality
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent extracts phosphonic acid or metal phosphonate species from the quantum dot surface using a treatment solution before applying the coating. This removal of interfering species enables the coating process to proceed with high precision and quality, ensuring that the protective layers are formed uniformly without defects caused by the harmful species.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent implements a preliminary surface treatment step that removes phosphonic acid or metal phosphonate species before the coating process. This preliminary action prepares the quantum dot surface for high-quality coating deposition, ensuring that the protective layers achieve the desired stability and manufacturing precision without interference from harmful species.

Inventive Principle:
Principle #10Preliminary action

3Duration of action of stationary object

If phosphonic acid or metal phosphonate species are used in quantum dot synthesis, then the quantum dots can be formed, but the lifetime and optical properties of the quantum dots are reduced

Engineering Contradiction:
Improvequantum dot lifetimeVSAvoidphosphonic acid or metal phosphonate species
Core Design Contradiction:
Duration of action of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The patent removes phosphonic acid or metal phosphonate species from the quantum dot surface through a treatment process that extracts these harmful species. This extraction extends the quantum dot lifetime by eliminating the harmful factors that would otherwise degrade the optical properties and reduce the duration of quantum dot action.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent performs a preliminary treatment to remove phosphonic acid or metal phosphonate species before the quantum dots are used in applications. This preliminary action prevents the harmful species from reducing the quantum dot lifetime and degrading optical properties, thereby extending the duration of effective quantum dot operation.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enhances the emission and lifetime of quantum dots by eliminating phosphonic acid or metal phosphonate species, allowing for improved optical properties and increased efficiency in applications such as lighting and diagnostics.

Implementation Method 1

the core particle is subjected to a high temperature process that forms a coating or layer or shell on the core particle to produce a core-shell quantum dot

Methodology Applied
Scientific EffectThermal deposition: Deposition (physical)

Data Source

PatentUS10096678B2Methods for coating semiconductor nanocrystals
Publication Date: 2018.10.09 SAMSUNG ELECTRONICS CO LTD

AI summary

A coated quantum dot and methods of making coated quantum dots are provided.