Matrix-Free Quantum Dot Output Coupling Element for Red and IR Light

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Solution Overview

Problem

Existing output coupling elements for optoelectronic components face challenges in efficiently decoupling light due to large refractive index differences at semiconductor chip interfaces, particularly for red and IR wavelength ranges, and current nanocomposites like zirconium oxide or titanium dioxide have limitations such as being applicable only as thin films and degrading under blue light or temperature.

Innovation Solution

A method involving the use of quantum dots with semiconductor cores, such as gallium phosphide or indium phosphide, is employed to create a matrix-free output coupling element. These quantum dots are suspended in a medium, applied directly to the component, and the medium is removed, resulting in a transparent, high refractive index element suitable for red and IR radiation decoupling.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If nanoparticles such as zirconium oxide or titanium dioxide are used as highly refractive additives for decoupling materials, then the refractive index is increased, but the material can only be applied as thin film and cannot be formed as lenses

Engineering Contradiction:
Improverefractive indexVSAvoidformability as lens
Core Design Contradiction:
Illumination intensityVSAdaptability or versatility

Solution Approach 1:

The patent changes the physical state parameter of the decoupling material from a solid nanoparticle suspension to an organic liquid crystal composition. This parameter change enables the material to be applied in thick layers and formed into lens shapes while maintaining high refractive index properties, resolving the contradiction between achieving high refractive index and forming functional optical elements like lenses

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite material system by combining organic liquid crystal molecules with high refractive index nanoparticles (such as titanium dioxide or zirconium oxide). This composite approach allows the material to simultaneously achieve high refractive index from the nanoparticles and lens-forming capability from the liquid crystal matrix, resolving the technical contradiction

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If organically loaded zirconium oxide nanoparticles are used, then refractive index is enhanced, but the material turns yellow under blue light and temperature tests

Engineering Contradiction:
Improverefractive indexVSAvoidcolor stability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent changes the chemical composition parameter by using purely inorganic liquid crystal materials instead of organic compounds. This parameter change eliminates the yellowing issue under blue light and temperature exposure while maintaining the high refractive index properties, thus resolving the contradiction between achieving high refractive index and maintaining color stability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent develops a composite material system combining inorganic liquid crystal molecules with high refractive index nanoparticles. This inorganic-inorganic composite approach provides both the high refractive index from the nanoparticles and the color stability from the inorganic liquid crystal matrix, resolving the technical contradiction

Inventive Principle:
Principle #40Composite materials

3Reliability

If matrix material such as silicone or epoxy is used to embed semiconductor chips, then environmental protection is improved, but light decoupling efficiency decreases due to refractive index differences

Engineering Contradiction:
Improveenvironmental protectionVSAvoidlight decoupling efficiency
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent replaces conventional organic matrix materials with a composite material system consisting of inorganic liquid crystal molecules and high refractive index nanoparticles. This composite material provides both environmental protection functions and superior light decoupling efficiency through its high refractive index, resolving the contradiction between reliability and illumination efficiency

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the refractive index parameter of the embedding material from 1.4-1.55 (conventional organics) to above 1.6 (inorganic liquid crystal with nanoparticles). This parameter change enables the material to simultaneously provide environmental protection and improved light decoupling efficiency, resolving the technical contradiction

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The method produces a highly efficient, matrix-free output coupling element that enhances light decoupling from semiconductor chips, maintaining transparency and refractive index properties, thus improving the performance of optoelectronic components like light-emitting diodes.

Implementation Method 1

providing quantum dots 2 with a core 3 having a semiconductor material

Methodology Applied
Scientific EffectQuantum confinement effect:

Implementation Method 2

The quantum dots are in particular transparent to radiation of the red and/or IR wavelength range

Methodology Applied
Scientific EffectLight absorption and emission: Absorption (EM radiation)

Implementation Method 3

producing a suspension 4 having the quantum dots 2 in a suspension medium 5

Methodology Applied
Scientific EffectSuspension: Suspension

Implementation Method 4

removing the suspension medium 5 to produce the output coupling element 1

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 5

Embodiments provide a significant increase in the refractive index by using, for example, gallium phosphide with a refractive index of 3.314 at 633 nm or indium phosphide with a refractive index of 3.536 at 633 nm

Methodology Applied
Scientific EffectRefraction: Refraction

Data Source

PatentUS11101412B2Method for producing an output coupling element for an optoelectronic component and output coupling element
Publication Date: 2021.08.24 OSRAM OLED
  • US11101412B2 patent drawing
  • US11101412B2 patent drawing
  • US11101412B2 patent drawing

AI summary

A method for producing an output coupling element and an output coupling element are disclosed. In an embodiment a method includes producing a suspension having quantum dots in a suspension medium, wherein each quantum dot comprises a core having a semiconductor material, directly applying the suspension onto a surface of an optoelectronic component and/or onto a surface of a carrier and removing the suspension medium for producing the output coupling element, wherein the output coupling element is matrix-free and transparent to radiation of a red range and/or a IR range.