Cadmium-Free Quantum Dot Emission Layer for BT.2020 Color Gamut

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Solution Overview

Problem

There is a need for a display device that utilizes environmentally friendly quantum dots, excluding cadmium, lead, or mercury, while achieving improved light emitting properties such as luminous efficiency, color reproducibility, and luminance, particularly in line with the BT2020 standard.

Innovation Solution

A display device incorporating a quantum dot emission layer with red, green, and blue light emitting quantum dots made from Group II-VI or Group III-V compounds, specifically ZnSe, ZnTe, ZnS, ZnSeTe, ZnSeS, InP, GaP, InAs, GaAs, InSb, GaSb, InGaP, InAsP, and InSbP, which are free from cadmium, lead, and mercury, dispersed in a polymer matrix, and configured to emit light with specific peak wavelengths and full width at half maximum (FWHM) values for enhanced performance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Illumination intensity

If quantum dots containing cadmium, lead, or mercury are used, then light emitting properties such as luminous efficiency and color reproducibility are improved, but environmental harm increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidenvironmental harm
Core Design Contradiction:
Illumination intensityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the material composition parameters of quantum dots by replacing toxic heavy metals (cadmium, lead, mercury) with environmentally friendly alternatives such as zinc selenide, zinc telluride, indium phosphide, and gallium nitride. This substitution maintains the quantum confinement effect and light emitting properties while eliminating environmental harm, achieving both high luminous efficiency and environmental sustainability

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures including core-shell quantum dots (e.g., CdSe core with ZnS shell, or environmentally friendly variants like InP core with ZnS shell) and quantum dots dispersed in polymer matrices. These composite structures enhance quantum yield, improve color reproducibility, and enable precise control over emission wavelengths while using less toxic materials

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If quantum dots containing cadmium, lead, or mercury are used, then color reproducibility is improved, but environmental harm increases

Engineering Contradiction:
Improvecolor reproducibilityVSAvoidenvironmental harm
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The patent achieves precise color reproduction by controlling the size and composition parameters of environmentally friendly quantum dots. By adjusting quantum dot diameter (affecting quantum confinement) and material composition (e.g., ZnSe, ZnTe, InP, GaN ratios), the emission wavelength is precisely tuned to match BT.2020 color space requirements, eliminating the need for toxic cadmium-based quantum dots

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material systems including quantum dots embedded in polymer matrices and core-shell structures to enhance color purity and reproducibility. The polymer matrix provides stable dispersion and protects quantum dot integrity, while core-shell structures enable precise spectral control, achieving BT.2020 color gamut coverage with environmentally friendly materials

Inventive Principle:
Principle #40Composite materials

3Object-affected harmful factors

If environmentally friendly quantum dots without cadmium, lead, or mercury are used, then environmental harm is reduced, but light emitting properties may deteriorate

Engineering Contradiction:
Improveenvironmental harmVSAvoidluminous efficiency
Core Design Contradiction:
Object-affected harmful factorsVSIllumination intensity

Solution Approach 1:

The patent optimizes the size and composition parameters of environmentally friendly quantum dots (ZnSe, ZnTe, InP, GaN-based) to achieve quantum confinement effects comparable to or exceeding traditional cadmium-based quantum dots. By precise control of particle diameter and material ratios, high quantum yields and luminous efficiency are achieved without toxic heavy metals

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs advanced composite material designs including core-shell structures (e.g., InP/ZnS, ZnSe/ZnS) and quantum dots dispersed in optimized polymer matrices. These composites enhance quantum yield, improve photostability, and maximize light emitting efficiency of environmentally friendly quantum dots, matching or exceeding the performance of toxic alternatives

Inventive Principle:
Principle #40Composite materials

4Object-affected harmful factors

If environmentally friendly quantum dots without cadmium, lead, or mercury are used, then environmental harm is reduced, but color reproducibility may deteriorate

Engineering Contradiction:
Improveenvironmental harmVSAvoidcolor reproducibility
Core Design Contradiction:
Object-affected harmful factorsVSManufacturing precision

Solution Approach 1:

The patent achieves precise color reproduction with environmentally friendly quantum dots by optimizing size distribution and material composition parameters. Through controlled synthesis, the emission spectra of ZnSe, ZnTe, InP, and GaN-based quantum dots are tuned to precisely match the red, green, and blue primary colors of the BT.2020 color space, achieving wide color gamut without toxic materials

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite material systems including quantum dots in polymer matrices and core-shell structures to enhance color purity and reproducibility. The polymer matrix ensures uniform dispersion and stable optical properties, while core-shell structures provide precise spectral control, achieving BT.2020 color gamut coverage with environmentally friendly compositions

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a display device with improved luminous efficiency, color reproducibility, and luminance, meeting or exceeding the BT2020 standard for color gamut, and ensuring environmental sustainability by avoiding the use of toxic heavy metals.

Implementation Method 1

A light source and a quantum dot emission layer on the light source. The quantum dot emission layer includes a first emission layer in a red pixel and a second emission layer in a green pixel

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 2

A semiconductor nanocrystal may exhibit electroluminescence and photoluminescence properties

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS11296294B2Display device comprising quantum dot emission layer
Publication Date: 2022.04.05 SAMSUNG ELECTRONICS CO LTD
  • US11296294B2 patent drawing
  • US11296294B2 patent drawing
  • US11296294B2 patent drawing

AI summary

A display device including a light source; and a quantum dot emission layer disposed on the light source, wherein the quantum dot emission layer includes a first emission layer disposed in a red pixel of the display device, and a second emission layer disposed in a green pixel of the display device, the light source includes a first portion configured to supply a first incident light to the first emission layer, a second portion configured to supply a second incident light to the second emission layer, and a third portion configured to supply a third light to a blue pixel of the display device, the first emission layer includes red light emitting quantum dots and the second emission layer includes green light emitting quantum dots, and each of the first portion, the second portion, and the third portion comprises a layer comprising blue light emitting quantum dots.