Quantum Dot Emission Layer Gradient for Charge Balance and Quenching Control

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Solution Overview

Problem

Quantum dot-based light emitting devices face challenges in achieving balanced charge transport and exciton confinement, leading to efficiency and lifespan issues due to the interference of organic ligands with charge flow and exciton quenching at the interface between the hole auxiliary layer and the emission layer.

Innovation Solution

A light emitting device structure with a sequential decrease in hole mobility across three emission layers, each with varying organic ligand content and halogen presence, is implemented, along with a metal oxide nanoparticle charge auxiliary layer, to optimize charge transport and exciton recombination within the emission layer.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If quantum dots with organic ligands are used in the emission layer, then quantum efficiency is improved through exciton confinement, but charge transport is interfered with and exciton quenching occurs at the interface

Engineering Contradiction:
Improvequantum efficiencyVSAvoidcharge transport interference and exciton quenching
Core Design Contradiction:
ReliabilityVSObject-generated harmful factors

Solution Approach 1:

The emission layer is divided into three distinct emission layers (first, second, and third emission layers) with sequentially decreasing hole mobility. Each emission layer contains quantum dots with different organic ligand contents, creating a gradient structure that segments the charge transport paths while maintaining exciton confinement throughout the layer.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

Different regions of the emission layer are assigned different organic ligand contents to optimize local properties. The first emission layer has lower organic ligand content for better charge transport, while subsequent layers have progressively higher content for improved exciton confinement, creating localized optimization throughout the structure.

Inventive Principle:
Principle #3Local quality

2Ease of manufacture

If a single emission layer with uniform organic ligand content is used, then manufacturing is simplified, but charge balance and exciton confinement cannot be simultaneously optimized

Engineering Contradiction:
Improveemission layer fabricationVSAvoidcharge balance and exciton confinement
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The emission layer is segmented into three sub-layers with distinct organic ligand contents and hole mobilities. This segmentation allows independent optimization of charge transport and exciton confinement in different regions while maintaining a systematic fabrication approach using sequential deposition or coating methods.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The organic ligand content parameter is systematically varied across the three emission layers, creating a gradient from lower to higher content. This parameter change enables continuous optimization of the balance between charge transport (favored by lower ligand content) and exciton confinement (favored by higher ligand content).

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This structure enhances electroluminescence properties, including efficiency and luminance, while extending the device's lifespan by promoting electron-hole recombination near the center of the emission layer, reducing exciton quenching and improving charge balance.

Implementation Method 1

Quantum dots are a nanocrystal semiconductor material having a diameter of less than or equal to around 10 nanometers (nm), and which exhibit quantum confinement effects

Methodology Applied
Scientific EffectQuantum confinement effect:

Implementation Method 2

Quantum dots emit light from excited electrons as the latter transition from a conduction band to a valence band

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Implementation Method 3

In order to improve the quantum efficiency, excitons may be confined in the emission layer, and in some instances, if the excitons are not confined in the emission layer for a variety of factors, the non-confinement may cause a problem such as exciton quenching

Methodology Applied
Scientific EffectExciton confinement:

Data Source

PatentUS11744096B2Light emitting device and display device including 1HE same
Publication Date: 2023.08.29 SAMSUNG ELECTRONICS CO LTD
  • US11744096B2 patent drawing
  • US11744096B2 patent drawing
  • US11744096B2 patent drawing

AI summary

A light emitting device including a first electrode and a second electrode, and an emission layer disposed between the first electrode and the second electrode and including quantum dots, a first charge auxiliary layer disposed between the emission layer and the first electrode, and a second charge auxiliary layer disposed between the emission layer and the second electrode, wherein the emission layer comprises a first emission layer contacting the first charge auxiliary layer, a second emission layer disposed on the first emission layer, and a third emission layer disposed on the second emission layer. The hole mobility of the first emission layer decreases sequentially from the first emission layer to the third emission layer.