Quantum Dot Patterning via Hydrogen Bond Self-Assembly

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Solution Overview

Problem

Current high-resolution patterning technologies for quantum dot light emitting diodes (QLEDs) are inadequate, limiting their mass production potential due to difficulties in achieving high-resolution patterning of quantum dot layers.

Innovation Solution

A method involving self-assembling nanoparticle layers on a substrate modified with specific bases connected by hydrogen bonds, allowing for precise patterning of quantum dot layers without inkjet printing or photolithography, using a process that includes modifying the substrate with a first base, depositing nanoparticles or quantum dots connected by a second base through hydrogen bonds, and removing them from non-predetermined areas using solvents.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional high-resolution patterning technologies (inkjet printing, photolithography) are used, then the manufacturing process can be implemented, but the resolution and patterning precision are insufficient

Engineering Contradiction:
Improvepatterning resolutionVSAvoidmanufacturing process complexity
Core Design Contradiction:
Manufacturing precisionVSEase of manufacture

Solution Approach 1:

The nanoparticle layer performs self-assembly through hydrogen bonding between complementary bases (A-T, C-G) to automatically form precise patterns without external intervention. The system uses its own molecular recognition capabilities to achieve patterning, eliminating the need for complex external patterning equipment and processes.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces mechanical patterning methods (inkjet printing, photolithography) with a chemical self-assembly mechanism. The hydrogen bond-based molecular recognition system substitutes for mechanical deposition and exposure processes, achieving higher resolution through chemical specificity rather than mechanical precision.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If hydrogen bond-based self-assembly is used, then high-resolution patterning is achieved, but the process requires precise substrate modification and base pairing

Engineering Contradiction:
Improvepatterning resolutionVSAvoidprocess steps complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The substrate is pre-modified with specific bases (A, T, C, or G) in predetermined patterns before nanoparticle deposition. This preliminary preparation enables the subsequent self-assembly process to proceed automatically without requiring complex real-time control or post-processing steps.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent utilizes specific chemical parameters (hydrogen bond compatibility between base pairs) to control the self-assembly process. By selecting appropriate base combinations and controlling environmental conditions (pH, temperature), the system achieves precise patterning through chemical parameter optimization rather than complex process control.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the formation of high-resolution quantum dot layers with improved performance and resolution, overcoming the limitations of existing technologies by achieving precise patterning without the need for inkjet printing or photolithography.

Implementation Method 1

a ligand of the nanoparticles including a second base, and the first base and the second base being connected by a hydrogen bond

Methodology Applied
Scientific EffectHydrogen bond: Chemical Bonding

Data Source

PatentUS11795386B2Method for patterning nanoparticle layer, quantum dot light emitting device and display device all fees
Publication Date: 2023.10.24 BOE TECHNOLOGY GROUP CO LTD
  • US11795386B2 patent drawing
  • US11795386B2 patent drawing
  • US11795386B2 patent drawing

AI summary

The present disclosure provides a method for patterning a nanoparticle layer, including steps of: (S1) connecting a first base to a surface of a predetermined area of a substrate, to form a substrate modified with the first base in the predetermined area of the substrate; (S2) depositing the nanoparticle in the predetermined area of the substrate, to form a nanoparticle layer in the predetermined area of the substrate by self-assembling, a ligand of the nanoparticle includes a second base, and the first base and the second base being connected by a hydrogen bond; and (S3) removing the nanoparticle in a non-predetermined area of the substrate.