Quantum Dot Ink Mixed Solvent Dispersion Stability

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Solution Overview

Problem

Conventional quantum dot ink compositions for quantum dot electroluminescent devices face challenges in achieving stable dispersion, precise landing properties, and film flatness during the inkjet printing process, leading to inadequate light emitting properties and device performance.

Innovation Solution

A quantum dot ink composition is developed using a mixed solvent system comprising a cycloalkane compound with a ring carbon and an aromatic hydrocarbon compound, combined with a fluorinated alcohol, which enhances dispersion stability and landing properties while maintaining film flatness by adjusting the surface tension and repulsive characteristics.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional quantum dot ink compositions are used, then the inkjet printing process can be performed, but the dispersion stability, landing properties, and film flatness are insufficient

Engineering Contradiction:
Improvedispersion stabilityVSAvoidlanding properties and film flatness
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The patent changes the chemical composition parameters of the solvent system by introducing a fluorinated alcohol component with specific molecular structure (containing CF3 group) into the quantum dot ink composition. This parameter change modifies the surface tension and repulsive characteristics of the ink, thereby improving both dispersion stability and landing properties simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite solvent system by combining fluorinated alcohol with traditional organic solvents (such as toluene, xylene, or cyclohexane). This composite material approach allows the ink composition to benefit from both the fluorinated alcohol's surface tension control and the traditional solvents' quantum dot solubility, resolving the contradiction between dispersion stability and manufacturing precision

Inventive Principle:
Principle #40Composite materials

2Manufacturing precision

If the surface tension and repulsive characteristics are adjusted, then the landing properties and film flatness improve, but the dispersion stability may be compromised

Engineering Contradiction:
Improvelanding accuracy and film flatnessVSAvoiddispersion stability
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent carefully controls the concentration parameter of fluorinated alcohol in the ink composition (typically 1-50% by volume). This parameter optimization ensures that the surface tension is reduced enough to improve landing properties and film flatness, while maintaining sufficient dispersion stability through the balanced composition

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides improved dispersion stability, precise landing accuracy, and enhanced film flatness, resulting in superior light emitting properties and device performance compared to conventional systems.

Implementation Method 1

a quantum dot ink composition having improved dispersion stability, landing properties of quantum dots, and film flatness may be provided

Methodology Applied
Scientific EffectSurface tension: Surface Tension

Data Source

PatentUS20230287231A1Quantum dot ink composition, and quantum dot electroluminescent device
Publication Date: 2023.09.14 SAMSUNG ELECTRONICS CO LTD
  • US20230287231A1 patent drawing
  • US20230287231A1 patent drawing

AI summary

A quantum dot ink composition including a plurality of quantum dots, and a mixed solvent including a Solvent a and a Solvent b, a quantum dot electroluminescent device including a light emitting layer formed from the quantum dot composition, and a method of making the quantum dot electroluminescent device are provided, where Solvent a is a cycloalkane compound with at least one ring carbon having a linear C4 to C16 alkyl group, an aromatic hydrocarbon compound having a linear C2 to C12 alkyl group, or a combination thereof, and Solvent b is a fluorinated alcohol.