Quantum Dot Emission Layer Composition With Ligand Scavenger

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Solution Overview

Problem

Existing display devices using organic compounds in self-luminescent displays face challenges in color reproducibility, reliability, and lifespan of light emitting diodes.

Innovation Solution

A quantum dot composition is used in the emission layer of a light emitting diode, featuring a hydrophilic group attached to the surface of modified quantum dots, combined with a ligand scavenger to enhance luminous efficiency through a nucleophilic attack reaction.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If organic compounds are used as light emitting materials in self-luminescent displays, then the display device can be manufactured with current technology, but color reproducibility and reliability are poor

Engineering Contradiction:
ImprovereliabilityVSAvoidease of manufacture
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the fundamental parameter of the light emitting material from organic compounds to quantum dots (inorganic nanocrystals). This material substitution fundamentally improves reliability and color reproducibility while maintaining manufacturability through solution-processing techniques that are already established in the display industry.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite material structures, specifically core-shell quantum dots (e.g., CdSe core with ZnS shell), to achieve both high reliability and good manufacturability. The composite structure enables precise control over optical properties while maintaining compatibility with existing manufacturing processes.

Inventive Principle:
Principle #40Composite materials

2Duration of action of stationary object

If organic compounds are used as light emitting materials, then the display device can be manufactured, but lifespan is limited

Engineering Contradiction:
ImprovelifespanVSAvoidease of manufacture
Core Design Contradiction:
Duration of action of stationary objectVSEase of manufacture

Solution Approach 1:

The patent changes the material parameter from organic to inorganic (quantum dot), which fundamentally extends the operational lifespan of the light emitting diode. Quantum dots exhibit superior stability against degradation compared to organic compounds, while still allowing solution-based manufacturing processes.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent replaces the short-lived organic light emitting materials with long-lived quantum dot materials that maintain stable performance over extended periods, directly addressing the lifespan limitation of organic-based displays.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

3Use of energy by moving object

If quantum dot composition with hydrophilic group is used, then luminous efficiency is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddevice complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent incorporates hydrophilic groups on quantum dot surfaces during the quantum dot synthesis process itself, rather than adding them later as a separate step. This preliminary action integrates the efficiency-enhancing feature into the base material fabrication, avoiding additional manufacturing complexity in the display device assembly process.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent modifies the surface properties of quantum dots by introducing hydrophilic groups, which changes the interaction with surrounding materials and enables improved luminous efficiency. This parameter change in surface chemistry achieves the desired efficiency without requiring complex device structure modifications.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Improves color reproducibility, reliability, and extends the life of display devices by utilizing a quantum dot composition with a hydrophilic group and ligand scavenger, enhancing luminous efficiency.

Implementation Method 1

the ligand scavenger is configured to induce a nucleophilic attack reaction on the ligand

Methodology Applied
Scientific EffectNucleophilic attack reaction: Chemical Bonding

Implementation Method 2

use of a quantum dot as the light emitting material in a light emitting diode could improve color reproducibility, reliability and the life of display devices

Methodology Applied
Scientific EffectLight emission: Light Emitting Diode

Data Source

PatentEP3772534B1Quantum dot composition, light emitting diode and display device including the light emitting diode
Publication Date: 2026.02.11 SAMSUNG DISPLAY CO LTD
  • EP3772534B1 patent drawingFigure 1
  • EP3772534B1 patent drawingFigure 2
  • EP3772534B1 patent drawingFigure 3~4

AI summary

A quantum dot composition of an embodiment includes: a quantum dot; a ligand combined with a surface of the quantum dot; and a ligand scavenger having a nucleophilic reaction group.