Quantum Dot Light-Emitting Element Ligand Dipole Gradient

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Solution Overview

Problem

The existing light-emitting elements with quantum dots have a low density of quantum dots towards the anode, leading to decreased exciton formation efficiency and overall light emission efficiency.

Innovation Solution

A light-emitting element with a light-emitting layer comprising a first layer with first quantum dots and a second layer closer to the electron-transport layer, both with different ligands having distinct dipole moments, to enhance quantum dot density and exciton formation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Use of energy by moving object

If the particle size of quantum dots is increased toward the anode to form a potential well, then light emission efficiency improves, but quantum dot density decreases leading to reduced exciton formation efficiency

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidquantum dot density
Core Design Contradiction:
Use of energy by moving objectVSQuantity of substance

Solution Approach 1:

The patent applies local quality by using different ligands with different dipole moments in different regions of the light-emitting layer. Specifically, ligands with larger dipole moments are used in the first light-emitting layer (closer to anode) while ligands with smaller dipole moments are used in the second light-emitting layer (closer to cathode), creating spatially varying properties that simultaneously maintain quantum dot density and form potential well

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the dipole moment parameter of ligands as a function of position within the light-emitting layer. By gradually varying the ligand dipole moment from smaller values near the cathode to larger values near the anode, the patent creates a continuous potential gradient that maintains quantum dot density while forming the necessary potential well for efficient light emission

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The proposed solution improves the light emission efficiency by maintaining a sufficient quantum dot density towards the anode and optimizing carrier transport and recombination.

Implementation Method 1

a dipole moment of the first ligands is larger than a dipole moment of the second ligands

Methodology Applied
Scientific EffectDipole moment:

Implementation Method 2

the particle size of the quantum dots is designed to gradually increase from toward the cathode to toward the anode, thereby forming a potential well

Methodology Applied
Scientific EffectQuantum confinement effect:

Implementation Method 3

a light-emitting element including a light-emitting layer containing quantum dots

Methodology Applied
Scientific EffectElectroluminescence: Electroluminescence

Data Source

PatentUS12274111B2Light-emitting element and light-emitting device
Publication Date: 2025.04.08 SHARP KK
  • US12274111B2 patent drawing
  • US12274111B2 patent drawing
  • US12274111B2 patent drawing

AI summary

A light-emitting element includes: a cathode; an anode; a light-emitting layer provided between the cathode and the anode and containing quantum dots; an electron-transport layer provided between the light-emitting layer and the cathode; and a hole-transport layer provided between the light-emitting layer and the anode. The light-emitting layer includes a first light-emitting layer containing first quantum dots to which first ligands are coordinated, and further includes a second light-emitting layer provided closer to the electron-transport layer than to the first light-emitting layer, and containing second quantum dots to which second ligands are coordinated. A dipole moment of the first ligands is larger than a dipole moment of the second ligands.