Quantum Dot Microemulsion Stability via Dissolution Medium

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Solution Overview

Problem

The stability and luminous efficiency of quantum dot luminescent materials are compromised due to poor compatibility with polymer matrices, leading to attenuation in their aging performance.

Innovation Solution

A quantum dot composition is developed, incorporating a microemulsion with quantum dots, a dissolution medium, and an emulsifier that encapsulates the dissolution medium, effectively isolating the quantum dots from the polymer precursor, thereby improving their stability and efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If quantum dots are dispersed directly in polymer precursor, then the polymer matrix can be formed, but the quantum dot efficiency attenuates due to poor compatibility and contact with polymer

Engineering Contradiction:
Improvequantum dot efficiency stabilityVSAvoiddispersion process simplicity
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent introduces a dissolution medium as an intermediary substance between quantum dots and polymer precursor. The quantum dots are first dissolved in the dissolution medium to form a quantum dot solution, which is then mixed with the polymer precursor. This intermediary medium improves compatibility and prevents direct harmful contact between quantum dots and polymer, maintaining quantum dot efficiency while enabling polymer matrix formation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Ease of manufacture

If quantum dots are dispersed in polymer precursor without dissolution medium, then the process is simple, but the quantum dots have poor compatibility leading to efficiency attenuation

Engineering Contradiction:
Improvedispersion process simplicityVSAvoidquantum dot efficiency stability
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The dissolution medium serves as a mediator that bridges the incompatibility between quantum dots and polymer precursor. By dissolving quantum dots in the dissolution medium first, the system achieves better compatibility when mixed with polymer precursor, preventing efficiency attenuation while maintaining a relatively simple two-step process.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If quantum dots are exposed to oxygen and water molecules, then the synthesis process is straightforward, but the quantum dot stability deteriorates due to unpaired electrons and unsaturated dangling bonds

Engineering Contradiction:
Improvesynthesis process straightforwardnessVSAvoidquantum dot chemical stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

The patent creates a protective environment by dissolving quantum dots in a dissolution medium that shields them from oxygen and water molecules. The dissolution medium forms a barrier that prevents harmful interactions with atmospheric contaminants, maintaining quantum dot stability during the dispersion and curing processes while allowing straightforward synthesis procedures.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The microemulsion structure enhances the long-term stability and luminous efficiency of the quantum dots by reducing contact with the polymer precursor, maintaining stable efficiency over time.

Implementation Method 1

the microemulsion includes quantum dots, a dissolution medium dissolving the quantum dots, and an emulsifier encapsulating the dissolution medium

Methodology Applied
Scientific EffectMicroemulsion: Microemulsion

Implementation Method 2

an emulsifier encapsulating the dissolution medium

Methodology Applied
Scientific EffectEncapsulation:

Implementation Method 3

a dissolution medium dissolving the quantum dots

Methodology Applied
Scientific EffectDissolution: Solvation

Data Source

PatentUS11091691B2Quantum dot composition, quantum dot luminescent material, preparation method thereof and light-emitting device containing the same
Publication Date: 2021.08.17 NAJING TECHNOLOGY CORPORATION LIMITED
  • US11091691B2 patent drawing
  • US11091691B2 patent drawing

AI summary

The disclosure provides a quantum dot composition, a quantum dot luminescent material, a preparation method thereof and a light-emitting device containing the same. The quantum dot composition includes a microemulsion, a polymer precursor dispersing the microemulsion, wherein the microemulsion includes quantum dots, a dissolution medium dissolving the quantum dots, and an emulsifier encapsulating the dissolution medium.