Quantum Dot MXene Composite Carrier Transport

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Solution Overview

Problem

Existing quantum dot light-emitting diodes face challenges with low carrier transport capacity and limited application due to the hindrance caused by long carbon chain oleic acid coatings on quantum dot surfaces, which affect device efficiency and stability.

Innovation Solution

A composite material comprising quantum dots connected to MXenes through coordination bonds, where the quantum dots are dispersed in an organic solvent with MXenes, and the mixture is reacted and separated to form a composite material that improves carrier transport and device efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If quantum dots are coated with long carbon chain oleic acid, then quantum dots exhibit good stability and optical properties, but carrier transport capacity is hindered and device efficiency is reduced

Engineering Contradiction:
Improvequantum dot stabilityVSAvoidcarrier transport capacity
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent extracts and removes the long carbon chain oleic acid coating from the quantum dot surface that hinders carrier transport. By eliminating this harmful coating layer while maintaining quantum dot stability through alternative surface treatment, the invention enables improved carrier transport capacity without sacrificing quantum dot stability

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the surface chemistry parameters of quantum dots by replacing long carbon chain oleic acid with shorter chain ligands or different surface treatments. This parameter change reduces the steric hindrance and electrical resistance at the quantum dot interface, thereby improving carrier transport capacity while maintaining colloidal stability

Inventive Principle:
Principle #35Parameter changes

2Device complexity

If conventional phosphors are used in display technology, then device structure is simpler, but color gamut is limited to 72% NTSC

Engineering Contradiction:
Improvebacklight structure complexityVSAvoidcolor gamut
Core Design Contradiction:
Device complexityVSIllumination intensity

Solution Approach 1:

The patent employs composite materials consisting of quantum dots combined with specific matrix materials or encapsulation structures. This composite approach enables the display to achieve wide color gamut (110-130% NTSC) while managing the complexity of the backlight structure through integrated design solutions

Inventive Principle:
Principle #40Composite materials

3Illumination intensity

If quantum dots are applied to active matrix light-emitting diode display, then color gamut reaches 130% NTSC and power consumption is reduced, but device efficiency and working stability have gaps with industrial requirements

Engineering Contradiction:
Improvecolor gamutVSAvoiddevice working stability
Core Design Contradiction:
Illumination intensityVSReliability

Solution Approach 1:

The patent introduces intermediary materials such as electron transport layers, hole transport layers, and encapsulation materials that mediate between the quantum dots and the electrode structures. These intermediary layers protect the quantum dots from degradation, improve interface contact, and enhance overall device stability and reliability for industrial application

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent uses composite material structures including quantum dots combined with stabilizing matrices, protective encapsulation layers, and functional transport materials. This composite approach simultaneously achieves wide color gamut (130% NTSC) and improved device working stability to meet industrial requirements

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composite material enhances photostability and quantum efficiency by forming fluorescence emission channels and improving carrier transport, leading to better light-emitting performance in quantum dot light-emitting diodes.

Implementation Method 1

metal atoms of the quantum dots are connected to surface groups of the MXenes through coordination bonds

Methodology Applied
Scientific EffectCoordination bonds: Chemical Bonding

Implementation Method 2

forming fluorescence emission channels and improving carrier transport, leading to better light-emitting performance

Methodology Applied
Scientific EffectFluorescence: Fluorescence

Data Source

PatentUS20240052237A1Composite material and preparation method therefor, and quantum dot light-emitting diode and preparation method therefor
Publication Date: 2024.02.15 TCL TECHNOLOGY GROUP CORPORATION
  • US20240052237A1 patent drawing
  • US20240052237A1 patent drawing
  • US20240052237A1 patent drawing

AI summary

The present application provides a composite material and a preparation method therefor, and a quantum dot light-emitting diode and a preparation method therefor, which relate to the field of display. The composite material comprises quantum dots and MXenes, metal atoms of the quantum dots are linked to surface groups of the MXenes by means of coordination bonds. An application of the composite material of the present application in a quantum dot light-emitting diode can increase the carrier injection speed and improve the performance of the quantum dot light-emitting diode.