Quantum Dot Phosphor Mixture Scattering for Cadmium Limits

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Solution Overview

Problem

Current quantum dot phosphors in optoelectronic components, such as LEDs, offer efficiency gains of 20% or more due to their narrow-band emission spectrum but are limited by cadmium content restrictions, leading to increased package size or reduced efficiency when trying to exploit their full potential.

Innovation Solution

A phosphor mixture comprising quantum dot phosphors and functional materials like aluminum oxide, titanium dioxide, or garnets that scatter electromagnetic radiation, increasing the utilization of quantum dot phosphors without exceeding cadmium limits, by adjusting particle size and density to enhance light conversion efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If quantum dot phosphors are used to achieve narrow-band emission spectrum, then conversion efficiency is improved by 20% or more, but cadmium content restrictions limit the actual efficiency gain to about 5%

Engineering Contradiction:
Improveconversion efficiencyVSAvoidcadmium content restriction
Core Design Contradiction:
ProductivityVSObject-affected harmful factors

Solution Approach 1:

The patent changes the physical and chemical parameters of the phosphor mixture by incorporating functional materials with specific properties (high refractive index, high density, scattering capability) to modify how quantum dot phosphors interact with light, thereby maximizing conversion efficiency within cadmium content limits

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite phosphor mixture combining quantum dot phosphors with functional materials (such as titanium dioxide, aluminum oxide, or garnets) that have complementary properties for light scattering and refractive index matching, achieving synergistic effects that overcome the limitations of quantum dot phosphors alone under cadmium restrictions

Inventive Principle:
Principle #40Composite materials

2Productivity

If package size is increased to overcome cadmium restrictions, then efficiency can be maintained, but cost and compatibility are reduced

Engineering Contradiction:
Improveconversion efficiencyVSAvoidpackage size
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent optimizes the concentration and size parameters of quantum dot phosphors and functional materials in the mixture to achieve maximum conversion efficiency in a compact form factor, eliminating the need for increased package size

Inventive Principle:
Principle #35Parameter changes

3Object-affected harmful factors

If conventional phosphors are used instead of quantum dot phosphors, then cadmium content is reduced, but conversion efficiency is limited

Engineering Contradiction:
Improvecadmium contentVSAvoidconversion efficiency
Core Design Contradiction:
Object-affected harmful factorsVSProductivity

Solution Approach 1:

The patent modifies the optical parameters of conventional phosphors by combining them with quantum dot phosphors and functional materials, creating a hybrid mixture that achieves both low cadmium content and high conversion efficiency through optimized light scattering and absorption properties

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite phosphor mixture that integrates conventional phosphors with quantum dot phosphors and functional materials, combining the advantages of each component to achieve both compliance with cadmium restrictions and maintenance of high conversion efficiency

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The phosphor mixture achieves higher efficiency in optoelectronic components by better utilizing quantum dot phosphors, allowing for increased conversion and weight of quantum dot phosphors within the permitted cadmium content, thereby enhancing the overall performance of LEDs without size or cost penalties.

Implementation Method 1

If the functional material is designed to scatter electromagnetic radiation, more significant scatter in the phosphor mixture reduces the free path length of the light through the material of the phosphor mixture

Methodology Applied
Scientific EffectScattering: Scattering

Implementation Method 2

The bandgap of the shell is adjusted via the material and size such that it absorbs the electromagnetic radiation of an excitation spectrum. The composition and dimensions of the core are in turn such that it emits a portion of the energy absorbed again as electromagnetic radiation in the emission spectrum

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Data Source

PatentUS11616175B2Luminophore mixture, conversion element and optoelectronic component
Publication Date: 2023.03.28 AMS OSRAM INT GMBH
  • US11616175B2 patent drawing
  • US11616175B2 patent drawing

AI summary

The invention relates to a luminophore mixture which comprises at least one quantum dot luminophore and at least one functional material, the functional material is formed such that it scatters electromagnetic radiation and/or has a high density.