Quantum Dot Photodetectors with Tuned Optical Paths for Infrared Sensitivity

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing photodetector elements, such as silicon photodiodes and InGaAs-based semiconductors, have low sensitivity in the infrared region and require high-cost processes, limiting their effectiveness in image sensors.

Innovation Solution

A photodetector element with a photoelectric conversion layer containing aggregates of semiconductor quantum dots, where the wavelength and optical path length satisfy specific relationships, enhancing optical interference and improving external quantum efficiency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If semiconductor quantum dots are used in the photoelectric conversion layer, then sensitivity in the infrared region is improved, but external quantum efficiency is insufficient

Engineering Contradiction:
ImprovesensitivityVSAvoidexternal quantum efficiency
Core Design Contradiction:
Measurement precisionVSReliability

Solution Approach 1:

The patent optimizes the optical path length parameter Lλ to satisfy specific relationships with the wavelength λ of target light (Expression 1: 0.05 + m/2 ≤ Lλ/λ ≤ 0.35 + m/2, where m is an integer). This parameter optimization enables the photodetector to achieve both high sensitivity in the infrared region and high external quantum efficiency by controlling the interaction between light and semiconductor quantum dots through precise optical path length adjustment.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If InGaAs-based semiconductor material is used to achieve high quantum efficiency, then external quantum efficiency is improved, but manufacturing cost increases due to high-cost processes such as epitaxial growth

Engineering Contradiction:
Improveexternal quantum efficiencyVSAvoidmanufacturing cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent replaces expensive InGaAs-based semiconductor materials requiring complex epitaxial growth processes with semiconductor quantum dots that can be manufactured through simpler, lower-cost methods. The quantum dot-based photoelectric conversion layer achieves comparable or superior external quantum efficiency while avoiding the high manufacturing costs associated with traditional infrared photodetector materials and processes.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent changes the material parameter from InGaAs-based semiconductors to semiconductor quantum dots, and optimizes the optical path length parameter Lλ to achieve high external quantum efficiency through a cost-effective manufacturing approach that does not require expensive epitaxial growth processes.

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If silicon photodiode is used, then manufacturing is easier and cost is lower, but sensitivity in the infrared region having a wavelength of 900 nm or more is insufficient

Engineering Contradiction:
Improvemanufacturing easeVSAvoidsensitivity
Core Design Contradiction:
Ease of manufactureVSMeasurement precision

Solution Approach 1:

The patent maintains the manufacturing simplicity and cost-effectiveness of silicon photodiodes while replacing the silicon photoelectric conversion layer with semiconductor quantum dots that are specifically optimized for infrared detection. This substitution preserves the ease of manufacturing through simple layer formation processes while dramatically improving sensitivity in the infrared region with wavelengths of 900 nm or more.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent creates a composite structure combining semiconductor quantum dots with a matrix material to form the photoelectric conversion layer. This composite approach maintains the manufacturing simplicity of traditional photodiode structures while incorporating quantum dot materials that provide enhanced infrared sensitivity, achieving both low-cost manufacturing and high sensitivity performance.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The photodetector element achieves high external quantum efficiency, particularly in the infrared region, with improved sensitivity and charge transport characteristics.

Implementation Method 1

a photoelectric conversion layer that contains aggregates of semiconductor quantum dots between a first electrode layer and a second electrode layer

Methodology Applied
Scientific EffectPhotoelectric effect: Photoelectric Effect

Implementation Method 2

a wavelength λ (nm) of target light to be detected by the photodetector element and an optical path length Lλ (nm) of light having the wavelength from a surface of the second electrode layer on a side of the photoelectric conversion layer to a surface of the photoelectric conversion layer on a side of the first electrode layer satisfy a relationship of the following Expression (1)

Methodology Applied
Scientific EffectOptical interference: Interference

Data Source

PatentUS12384962B2Photodetector element, manufacturing method for photodetector element, and image sensor
Publication Date: 2025.08.12 FUJIFILM CORP
  • US12384962B2 patent drawing
  • US12384962B2 patent drawing
  • US12384962B2 patent drawing

AI summary

A photodetector element includes a photoelectric conversion layer that contains aggregates of semiconductor quantum dots between a first electrode layer and a second electrode layer, where the first electrode layer is provided on a light incident side with respect to the second electrode layer, and a wavelength λ (nm) of target light to be detected by the photodetector element and an optical path length Lλ (nm) of light having the wavelength λ, from a surface of the second electrode layer on a side of the photoelectric conversion layer to a surface of the photoelectric conversion layer on a side of the first electrode layer satisfy a relationship of the following Expression (1). m is an integer of 0 or more.0.05+m/2≤Lλ/λ≤0.35+m/2  (1)