Quantum Dot Polymer Composite for Display Luminous Efficiency

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Solution Overview

Problem

Current technologies face challenges in developing a quantum dot-polymer composite with enhanced properties suitable for various display devices, particularly in achieving improved luminous efficiency and color reproducibility while maintaining high brightness and wide viewing angles.

Innovation Solution

A photosensitive composition comprising quantum dots, a luminescent material, a carboxylic acid group-containing binder, a photopolymerizable monomer, and a photoinitiator, where the luminescent material overlaps spectrally with the quantum dots to enhance light absorption and emission, and the binder ensures dispersion stability without surface treatment, allowing for pattern formation in an environmentally friendly manner.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If quantum dots are used in display devices, then color reproducibility and luminous efficiency are improved, but absorption of excitation light is insufficient

Engineering Contradiction:
Improveabsorption of excitation lightVSAvoidluminous efficiency
Core Design Contradiction:
Loss of energyVSReliability

Solution Approach 1:

The patent combines quantum dots with luminescent materials in a hybrid composite structure. The luminescent material absorbs excitation light and transfers energy to the quantum dots, which then emit light. This merging of absorption and emission functions resolves the contradiction by ensuring both sufficient light absorption and high luminous efficiency are achieved simultaneously.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention uses a composite material system consisting of quantum dots dispersed in a polymer matrix containing luminescent materials. This composite structure allows the luminescent material to handle excitation light absorption while quantum dots maintain their high-color-purity emission, thereby resolving the trade-off between absorption efficiency and luminous performance.

Inventive Principle:
Principle #40Composite materials

2Reliability

If quantum dot-polymer composite is prepared, then enhanced properties are achieved, but surface treatment is required which complicates the process

Engineering Contradiction:
Improveenhanced propertiesVSAvoidsurface treatment requirement
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent employs a polymer matrix that inherently provides stabilization and dispersion of quantum dots without requiring additional surface treatment of the quantum dots themselves. The polymer system self-services by providing the necessary environment for quantum dot stability, eliminating complex surface modification steps and simplifying the manufacturing process while maintaining enhanced properties.

Inventive Principle:
Principle #25Self-service

3Reliability

If quantum dots are dispersed in polymer matrix, then luminous efficiency is improved, but dispersion stability is poor without surface treatment

Engineering Contradiction:
Improveluminous efficiencyVSAvoiddispersion stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The invention creates a composite material where quantum dots are dispersed in a polymer matrix containing luminescent materials and functional additives. This composite structure provides both the luminous efficiency benefits of quantum dots and the dispersion stability of the polymer system, resolving the contradiction between achieving high luminous efficiency and maintaining stable dispersion without surface treatment.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The polymer matrix acts as an intermediary between quantum dots and the surrounding environment. It provides a stabilizing medium that maintains quantum dot dispersion stability while allowing the quantum dots to function at high luminous efficiency, eliminating the need for surface treatment of the quantum dots themselves.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution provides a quantum dot-polymer composite with increased absorption of excitation light, enhanced photoconversion efficiency, and improved luminous efficiency, maintaining high brightness and wide viewing angles without adverse effects on emitted light properties.

Implementation Method 1

The quantum dot absorbs at least a portion of light emitted from the luminescent material

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Implementation Method 2

a luminescent material except for a quantum dot (e.g., a semiconductor nanocrystal particle)... the luminescent material includes a fluorophore

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 3

a photopolymerizable monomer including a carbon-carbon double bond; and a photoinitiator

Methodology Applied
Scientific EffectPhotopolymerisation: Photopolymerisation

Data Source

PatentUS10782611B2Quantum dots, a composition or composite including the same, and en electronic device including the same
Publication Date: 2020.09.22 SAMSUNG ELECTRONICS CO LTD
  • US10782611B2 patent drawing
  • US10782611B2 patent drawing
  • US10782611B2 patent drawing

AI summary

A photosensitive composition, a quantum dot polymer composite pattern prepared therefrom, and a layered structure and an electronic device including the same. The photosensitive composition includes plurality of quantum dots; a luminescent material other than a quantum dot; a carboxylic acid group containing binder; a photopolymerizable monomer having a carbon-carbon double bond; and a photoinitiator, and the luminescent material comprises a fluorophore, a nanosized inorganic phosphor, or a combination thereof.