Quantum Dot Print Material Composition for Stable Particle Dispersion

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Solution Overview

Problem

Maintaining the dispersion of solids, such as quantum dots and light-scattering particles, in the matrix material used in inkjet printing is a challenge, leading to maldistribution and instability in print materials.

Innovation Solution

A print material composition comprising a vinylic molecule, a vinylic cross-linker molecule with multiple vinyl groups, quantum dots, light-scattering particles with a specific surface composition, and a dispersant with chemical affinity matched to the surface composition, along with a method of applying and polymerizing this mixture to form a stable material layer on a substrate.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If solids are dispersed in matrix material for inkjet printing, then the print material can be applied to substrate, but the solids aggregate and disperse unevenly during storage and printing

Engineering Contradiction:
ImproveprintabilityVSAvoiddispersion stability
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

A dispersant is introduced as an intermediary substance between the solids (quantum dots and light-scattering particles) and the matrix material. The dispersant has a surface composition matched to the solids and provides steric stabilization, preventing aggregation while maintaining dispersion during storage and printing operations.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The print material is formulated as a composite system containing multiple components: vinylic molecules, cross-linker molecules, quantum dots, light-scattering particles, and dispersant. This composite structure allows each component to perform its specific function while working together to achieve both stability and printability.

Inventive Principle:
Principle #40Composite materials

2Productivity

If quantum dots and light-scattering particles are mixed in curable material, then the material can be printed, but the particles settle and separate over time

Engineering Contradiction:
Improveprinting capabilityVSAvoidstorage stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The dispersant acts as a mediator that adsorbs to the particle surfaces and extends into the matrix material, creating a steric barrier that prevents particle settling and separation. This allows the mixture to remain stable during storage while maintaining its printable properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The viscosity of the curable material is adjusted to an optimal range (5-500 cP) that balances printability with resistance to particle settling. The dispersant concentration is also optimized to provide sufficient stabilization without compromising the printing process.

Inventive Principle:
Principle #35Parameter changes

3Manufacturing precision

If high concentration of solids is used in print material, then the optical performance is improved, but the dispersion becomes unstable and particles aggregate

Engineering Contradiction:
Improveoptical performanceVSAvoiddispersion uniformity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The dispersant provides steric stabilization that becomes increasingly important at higher solid concentrations. By adsorbing to particle surfaces and creating physical barriers, the dispersant prevents aggregation even when particles are closely spaced at high loading levels.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The dispersant creates localized protective layers around each particle surface, ensuring that even at high concentrations where particles are close together, each particle maintains its individuality and does not aggregate with neighbors.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution stabilizes the dispersion of quantum dots and light-scattering particles, preventing aggregation and ensuring uniform distribution, resulting in stable and effective print materials for applications like display panels.

Implementation Method 1

a dispersant having a chemical affinity that is matched to the surface composition

Methodology Applied
Scientific EffectChemical affinity: Adsorption

Implementation Method 2

polymerizing the mixture to form a material layer on the substrate

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Implementation Method 3

a light-scattering particle having a surface composition

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentUS11945961B2Stabilized print materials
Publication Date: 2024.04.02 KATEEVA INC
  • US11945961B2 patent drawing
  • US11945961B2 patent drawing
  • US11945961B2 patent drawing

AI summary

A print material includes a vinylic molecule, a vinylic cross-linker molecule having a plurality of vinyl groups, a quantum dot, a light-scattering particle having a surface composition, and a dispersant having a chemical affinity matched to the surface composition. Methods of making and using such print materials are also described.