Quantum Rod Alignment via Liquid Crystal Ligands

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Solution Overview

Problem

Existing methods for aligning quantum rods in light-emitting devices suffer from low efficiency due to inadequate orientation alignment, physical damage to substrates, and long alignment times, limiting device performance.

Innovation Solution

The use of liquid crystal ligands with specific chemical structures to align quantum rods, enabling high in-plane orientation and improving the efficiency of light-emitting devices by facilitating uniform alignment without substrate damage.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If quantum rods are aligned using magnetic fields or micro grooves, then orientation alignment is achieved, but device complexity increases or substrate damage occurs

Engineering Contradiction:
Improveorientation alignmentVSAvoidelectrode insertion
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent introduces liquid crystal ligands as intermediary substances that mediate the alignment of quantum rods. These ligands self-assemble to form ordered structures that guide quantum rod orientation without requiring external magnetic fields, micro grooves, or additional electrodes, thereby achieving precise alignment while simplifying device complexity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces mechanical alignment methods (such as micro groove formation) and external field applications (magnetic fields requiring electrodes) with a chemical self-assembly approach using liquid crystal ligands. This substitution eliminates the need for complex mechanical structures and electrical components while achieving the desired orientation alignment

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If quantum rods are aligned using micro grooves, then orientation is achieved, but substrate is physically damaged

Engineering Contradiction:
Improveorientation alignmentVSAvoidsubstrate damage
Core Design Contradiction:
Manufacturing precisionVSObject-affected harmful factors

Solution Approach 1:

The liquid crystal ligands act as intermediary agents that enable quantum rod alignment through molecular self-assembly on the substrate surface without requiring physical groove formation. This chemical mediation approach achieves precise orientation alignment while completely avoiding the mechanical damage to substrates that would result from etching or forming micro grooves

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If quantum rods are aligned using self assembly, then alignment is achieved, but time consumption increases

Engineering Contradiction:
ImprovealignmentVSAvoidalignment time
Core Design Contradiction:
Manufacturing precisionVSLoss of time

Solution Approach 1:

The patent modifies key parameters of the self-assembly process by designing liquid crystal ligands with specific molecular structures and properties that accelerate the alignment kinetics. By changing parameters such as ligand length, functional groups, and molecular geometry, the patent achieves rapid self-assembly that reduces alignment time while maintaining high precision orientation

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite liquid crystal ligand structures combining different functional moieties that work synergistically to accelerate alignment. The composite nature of these ligands, with specific head groups, linker regions, and tail groups, enables faster self-assembly kinetics compared to simpler ligand structures, thereby reducing the time required to achieve alignment

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The alignment of quantum rods using liquid crystal ligands enhances the stability and efficiency of light-emitting devices by achieving high in-plane orientation, thereby improving the overall performance and reducing alignment time.

Implementation Method 1

at least one liquid crystal ligand linked to the surface of the nanoparticle

Methodology Applied
Scientific EffectLiquid crystal: Liquid Crystals

Data Source

PatentUS11802242B2Quantum rod, and light-emitting device, optical member, and apparatus, including the same
Publication Date: 2023.10.31 SAMSUNG DISPLAY CO LTD
  • US11802242B2 patent drawing
  • US11802242B2 patent drawing
  • US11802242B2 patent drawing

AI summary

A quantum rod includes a nanoparticle, and at least one ligand linked to the surface of the nanoparticle and represented by Formula 1.R1-(L1)b1-(A1)a1-(L2)b2-(A2)a2-(L3)b3-T1.  Formula 1A light-emitting device, an optical member, and an apparatus, each includes the quantum rod.