Synthetic Quartz Glass Diffuser for UV Resistance

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Solution Overview

Problem

Existing diffuser materials, such as Spectralon, exhibit changing optical properties over time, low mechanical stability, and limited temperature stability, failing to meet requirements for high corrosive, mechanical, and thermal loads, as well as UV radiation resistance.

Innovation Solution

A diffuser material made from synthetically produced quartz glass with a hydroxyl group content of at least 200 wt. ppm and pores with at least 80% having a maximum dimension of less than 20 μm, ensuring Lambertian behavior, high UV radiation resistance, and mechanical and thermal stability, produced through a method involving comminution of quartz glass, wet grinding, and sintering in a neon atmosphere.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If Spectralon (sintered PTFE) is used as diffuser material, then diffuse reflectivity and Lambertian behavior are achieved, but mechanical stability and temperature stability deteriorate

Engineering Contradiction:
Improvediffuse reflectivity stabilityVSAvoidmechanical stability
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent changes the material parameter from PTFE plastic to synthetically produced quartz glass, fundamentally altering the material composition to achieve both high diffuse reflectivity and superior mechanical/thermal stability. The quartz glass material maintains the optical scattering properties while providing enhanced mechanical strength and temperature resistance up to 1000°C.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite structure by combining synthetically produced quartz glass particles with controlled pore formation. The material consists of glass particles with interconnected pores filled with air or other gases, creating a composite structure that provides both optical scattering (diffuse reflectivity) and mechanical stability through the glass matrix.

Inventive Principle:
Principle #40Composite materials

2Reliability

If Spectralon (sintered PTFE) is used as diffuser material, then diffuse reflectivity is achieved, but temperature stability deteriorates

Engineering Contradiction:
Improvediffuse reflectivity stabilityVSAvoidtemperature stability
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The patent changes the material parameter from PTFE plastic to synthetically produced quartz glass, fundamentally altering the material composition to achieve both high diffuse reflectivity and superior mechanical/thermal stability. The quartz glass material maintains the optical scattering properties while providing enhanced mechanical strength and temperature resistance up to 1000°C.

Inventive Principle:
Principle #35Parameter changes

3Reliability

If porous structure is created for diffuse reflection, then Lambertian behavior is achieved, but mechanical stability deteriorates

Engineering Contradiction:
ImproveLambertian reflection behaviorVSAvoidmechanical stability
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The patent utilizes a porous structure formed from synthetically produced quartz glass particles. The pores are created during the sintering process, forming an interconnected network that scatters light effectively for Lambertian behavior. The glass matrix provides structural support, maintaining mechanical stability despite the porous architecture.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent creates a composite structure by combining synthetically produced quartz glass particles with controlled pore formation. The material consists of glass particles with interconnected pores filled with air or other gases, creating a composite structure that provides both optical scattering (diffuse reflectivity) and mechanical stability through the glass matrix.

Inventive Principle:
Principle #40Composite materials

4Strength

If synthetic quartz glass is used instead of Spectralon, then mechanical and thermal stability are improved, but manufacturing complexity increases

Engineering Contradiction:
Improvemechanical stabilityVSAvoidmanufacturing process complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies preliminary action by pre-sintering the quartz glass particles before final forming. The synthesis process involves multiple staged sintering operations where particles are progressively densified and bonded. This preliminary sintering creates a green body that can then be easily formed into final shapes, reducing overall manufacturing complexity.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent changes the material parameter from PTFE plastic to synthetically produced quartz glass, fundamentally altering the material composition to achieve both high diffuse reflectivity and superior mechanical/thermal stability. The quartz glass material maintains the optical scattering properties while providing enhanced mechanical strength and temperature resistance up to 1000°C.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The diffuser material achieves stable diffuse reflectivity and transmissivity over a wide wavelength range, enhanced UV radiation resistance, and improved mechanical and thermal stability, suitable for high-stress applications including spectroscopy and space applications.

Implementation Method 1

The porous structure creates multiple internal reflections on the surface and within a thin layer below said surface, so that light impinging on the surface is diffusely reflected

Methodology Applied
Scientific EffectDiffuse reflection: Reflection

Implementation Method 2

The ideally diffusely reflecting surface is non-specular and reflects optical radiation according to Lambert's law

Methodology Applied
Scientific EffectLambertian reflection: Reflection

Implementation Method 3

the green body is processed by sintering into the diffuser material

Methodology Applied
Scientific EffectSintering: Sintering

Implementation Method 4

The diffuser material achieves stable diffuse reflectivity and transmissivity over a wide wavelength range, enhanced UV radiation resistance

Methodology Applied
Scientific EffectUV radiation resistance: Absorption (EM radiation)

Data Source

PatentUS11390556B2Diffuser material of synthetically produced quartz glass and method for the manufacture of a molded body consisting fully or in part thereof
Publication Date: 2022.07.19 HERAEUS QUARZGLAS GMBH & CO KG
  • US11390556B2 patent drawing
  • US11390556B2 patent drawing
  • US11390556B2 patent drawing

AI summary

A diffuser material of synthetically produced, pore-containing quartz glass and a method for the manufacture of a molded body consisting fully or in part thereof. The diffuser material has a chemical purity of at least 99.9% SiO2, a cristobalite content of not more than 1%, and a density in the range of 2.0 to 2.18 g/cm3. Starting therefrom, to indicate a diffuser material which is improved with respect to diffuse reflectivity with Lambertian behavior over a wide wavelength range, high material homogeneity and UV radiation resistance, the quartz glass has a hydroxyl group content in the range of at least 200 wt. ppm and at least 80% of the pores have a maximum pore dimension of less than 20 μm.