Radial Flow Fixed Bed Reactor for Paraffin Conversion

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Solution Overview

Problem

The transportation of gas phase petroleum products from oil extraction sites is often cost-prohibitive due to logistical challenges, leading to the practice of burning or flaring these products, which wastes energy and poses health hazards, especially in remote locations where infrastructure for purification and fractionation is lacking.

Innovation Solution

A fixed bed radial flow reactor system is employed to convert C3+ paraffins into liquid aromatics, such as benzene, toluene, and xylene, using a specific geometry and catalyst configuration that minimizes pressure drop and allows for efficient control of reaction conditions, enabling the production of transportable liquid products.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If gas phase petroleum products are transported from oil extraction sites, then the carbon content can be utilized, but transportation costs and logistical challenges make it cost-prohibitive

Engineering Contradiction:
Improveenergy waste from flaringVSAvoidtransportation cost
Core Design Contradiction:
Loss of energyVSEase of manufacture

Solution Approach 1:

The invention changes the physical state parameter of the hydrocarbon feedstock by converting gas phase products into liquid phase aromatics through catalytic conversion. This phase change enables the products to be transported via existing liquid transportation infrastructure at lower costs, while also preventing energy waste from flaring by utilizing the carbon content in the converted liquid products

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention introduces a catalytic conversion system as an intermediary process between gas production and transportation. The reactor system with specific catalyst beds acts as a mediator that transforms the gas phase hydrocarbons into liquid aromatics, creating a bridge that allows utilization of gas phase products without requiring direct gas transportation infrastructure

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If a fixed bed reactor is used for paraffin conversion, then catalyst bed stability is maintained, but pressure drop across the catalyst bed increases

Engineering Contradiction:
Improvecatalyst bed stabilityVSAvoidpressure drop
Core Design Contradiction:
ReliabilityVSStress or pressure

Solution Approach 1:

The invention divides the catalyst bed into multiple segmented sections with different catalyst types arranged in sequence. This segmentation allows each catalyst bed section to perform a specific conversion function while maintaining overall system stability. The segmented structure also enables better pressure management by distributing the conversion process across multiple stages rather than one large pressure drop zone

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from traditional axial flow through the catalyst bed to radial flow geometry, changing the flow dimension. This radial configuration allows gas to flow perpendicular to the catalyst bed axis, significantly reducing the linear distance through the catalyst and thereby reducing pressure drop while maintaining catalyst bed stability and conversion efficiency

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Stress or pressure

If radial flow geometry is used, then pressure drop is reduced, but reactor design complexity increases

Engineering Contradiction:
Improvepressure dropVSAvoidreactor design
Core Design Contradiction:
Stress or pressureVSDevice complexity

Solution Approach 1:

The invention designs the radial flow reactor to serve multiple functions simultaneously: it performs catalytic conversion, enables radial flow pattern for reduced pressure drop, and accommodates multiple catalyst beds in a single integrated structure. This multi-functionality reduces the need for separate equipment for each function, thereby managing overall system complexity despite the advanced radial geometry

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The reactor design nests multiple catalyst beds within the radial flow structure, with each catalyst bed section contained within the same radial flow path. This nesting approach allows complex multi-catalyst functionality to be achieved within a single reactor vessel, reducing the number of separate reactor units needed and managing design complexity through hierarchical integration

Inventive Principle:
Principle #7Nested doll (Nesting)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach allows for the conversion of gas phase products into transportable liquid aromatics with reduced pressure drop and improved operational efficiency, reducing the need for flaring and associated environmental hazards, while enabling cost-effective processing and transport of valuable hydrocarbons.

Implementation Method 1

The inner annular volume can further comprise gas phase hydrocarbons, at least 5 vol % of the gas phase hydrocarbons comprising C3+ paraffins... exposing a feed to a catalyst in a fixed bed radial flow reactor... to convert the gas phase products to liquid products

Methodology Applied
Scientific EffectCatalysis: Catalysis

Data Source

PatentUS10913042B2Fixed bed radial flow reactor for light paraffin conversion
Publication Date: 2021.02.09 EXXONMOBIL TECHNOLOGY & ENGINEERING CO
  • US10913042B2 patent drawing
  • US10913042B2 patent drawing
  • US10913042B2 patent drawing

AI summary

Systems and methods are provided for conversion of light paraffinic gases to form liquid products in a process performed in a fixed bed radial-flow reactor. The light paraffins can correspond to C3+ paraffins. Examples of liquid products that can be formed include C6-C12 aromatics, such as benzene, toluene, and xylene. The fixed bed radial-flow reactor can allow for improved control over the reaction conditions for paraffin conversion in spite of the fixed bed nature of the reactor. This can allow the process to operate with improved efficiency while reducing or minimizing the complexity of operation relative to non-fixed bed reactor systems.